Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
USE OF OIL IN GENERATORS.--Calcium carbide is a material which is only
capable of attack for the purpose of evolving acetylene by a liquid that
is essentially water, or by one that contains some water mixed with it.
Oils and the like, or even such non-aqueous liquids as absolute alcohol,
have no effect upon carbide, except that the former naturally make it
greasy and somewhat more difficult to moisten. This last property has
been found of service in acetylene generation, especially on the small
scale; for if carbide is soaked in, or given a coating of, some oil, fat,
or solid hydrocarbon like petroleum, cocoanut oil, or paraffin wax, the
substance becomes comparatively indifferent towards water vapour or the
moisture present in the air, while it still remains capable of complete,
albeit slow, decomposition by liquid water when completely immersed
therein. The fact that ordinary calcium carbide is attacked so quickly by
water is really a defect of the substance; for it is to this extreme
rapidity of reaction that the troubles of overheating are due. Now, if
the basket in the generator B^1 of Fig. 2, or, indeed, the carbide store
in any of the carbide-to-water apparatus, is filled with a carbide which
has been treated with oil or wax, as long as the water-level stands at
_l'_ and _l"_ or the carbide still remains in the hopper, it is
essentially unattacked by the vapour arising from the liquid; but
directly the basket is submerged, or the lumps fall into the water,
acetylene is produced, and produced more slowly and regularly than
otherwise. Again, oils do not mix with water, but usually float thereon,
and a mass of water covered by a thick film or layer of oil does not
evaporate appreciably. If, now, a certain quantity of oil, say lamp
paraffin or mineral lubricating oil, is poured on to the water in B^1,
Fig. 2, it moves upwards and downwards with the water. When the water
takes the position _l_, the oil is driven upwards away from the
basket of carbide, and acetylene is generated in the ordinary manner; but
when the water falls to _l"_ the oil descends also, rinses off much
of the adhering water from the carbide lumps, covers them with a greasy
film, and almost entirely stops generation till it is in turn washed off
by the next ascent of the water. Similarly, if the carbide in generators
F, G, and H (also K) has been treated with a solid or semi-solid grease,
it is practically unattacked by the stream of warm damp gas, and is only
decomposed when the liquid itself arrives in the basket. For the same
reason treated carbide can be kept for fairly long periods of time, even
in a drum with badly fitting lid, without suffering much deterioration by
the action of atmospheric moisture. The problem of acetylene generation
is accordingly simplified to a considerable degree by the use of such
treated carbide, and the advantage becomes more marked as the plant
decreases in size till a portable apparatus is reached, because the
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