Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
EFFECT OF STORAGE IN GASHOLDER ON ACETYLENE.--It is perfectly true, as
has been stated elsewhere, that the gas coming from an acetylene
generator loses some of its illuminating power if it is stored over water
for any great length of time; such loss being given by Nichols as 94 per
cent, in five months, and having been found by one of the authors as 0.63
per cent. per day--figures which stand in fair agreement with one
another. This wastage is not due to any decomposition of the acetylene in
contact with water, but depends on the various solubilities of the
different gases which compose the product obtained from commercial
calcium carbide. Inasmuch as an acetylene evolved in the best generator
contains some foreign ingredients, and inasmuch as an inferior product
contains more (_cf._ Chapter V.), the contents of a holder are never
pure; but as those contents are principally made up of acetylene itself,
that gas stands at a higher partial pressure in the holder than the
impurities. Since acetylene is more soluble in water than any of its
diluents or impurities, sulphuretted hydrogen and ammonia excepted, and
since the solubility of all gases increases as the pressure at which they
are stored rises, the true acetylene in an acetylene holder dissolves in
the water more rapidly and comparatively more copiously than the
impurities; and thus the acetylene tends to disappear and the impurities
to become concentrated within the bell. Simultaneously at the outer part
of the seal, air is dissolved in the water; and by processes of diffusion
the air so dissolved passes through the liquid from the outside to the
inside, where it escapes into the bell, while the dissolved acetylene
similarly passes from the inside to the outside of the seal, and there
mingles with the atmosphere. Thus, the longer a certain volume of
acetylene is stored over water, the more does it become contaminated with
the constituents of the atmosphere and with the impurities originally
present in it; while as the acetylene is much more soluble than its
impurities, more gas escapes from, than enters, the holder by diffusion,
and so the bulk of stored gas gradually diminishes. However, the figures
previously given show that this action is too slow to be noticeable in
practice, for the gas is never stored for more than a few days at a time.
The action cannot be accepted as a valid argument against the employment
of a holder in acetylene plant. Such deterioration and wastage of gas may
be reduced to some extent by the use of a film of some cheap and
indifferent oil floating on the water inside an acetylene holder; the
economy being caused by the lower solubility of acetylene in oils than in
aqueous liquids not saturated with some saline material. Probably almost
any oil would answer equally well, provided it was not volatile at the
temperature of the holder, and that it did not dry or gum on standing,
_e.g._, olive oil or its substitutes; but mineral lubricating oil is
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