Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
generator-house may eventually become so offensive to the nostrils that
the liquid has to be renewed; but when this happens it is due to the
accumulation in the water of the water-soluble impurities of the crude
acetylene. If, as should be done, the gas is passed through a washer or
condenser containing much water before it enters the holder the
sulphuretted hydrogen and ammonia will be extracted, and the seal will
not acquire an obnoxious odour for a very long time.
Four principal substances have been proposed for lowering the freezing-
point of the water in an acetylene-holder seal; common salt (sodium
chloride), calcium chloride (not chloride of lime), alcohol (methylated
spirit), and glycerin. A 10 per cent. solution of common salt has a
specific gravity of 1.0734, and does not solidify above -6° C. or 21.2°
F.; a 15 per cent. solution has a density of 1.111, and freezes at -10°
C. or 14° F. Common salt, however, is not to be recommended, as its
solutions always corrode iron and steel vessels more or less quickly.
Alcohol, in its English denatured form of methylated spirit, is still
somewhat expensive to use, but it has the advantage of not increasing the
viscosity of the water; so that a frost-proof mixture of alcohol and
water will flow as readily through minute tubes choked with needle-
valves, or through felt and the like, or along wicks, as will plain
water. For this reason, and for the practically identical one that it is
quite free from dirt or insoluble matter, diluted spirit is specially
suitable for the protection of the water in cyclists' acetylene lamps,
[Footnote: As will appear in Chapter XIII., there is usually no holder in
a vehicular acetylene lamp, all the water being employed eventually for
the purpose of decomposing the carbide. This does not affect the present
question. Dilute alcohol does not attack calcium carbide so energetically
as pure water, because it stands midway between pure water and pure
alcohol, which is inert. The attack, however, of the carbide is as
complete as that of pure water, and the slower speed thereof is a
manifest advantage in any holderless apparatus.] where strict economy is
less important than smooth working. For domestic and larger installations
it is not indicated. As between calcium chloride and glycerin there is
little to choose; the former will be somewhat cheaper, but the latter
will not be prohibitively expensive if the high-grade pure glycerins of
the pharmacist are avoided. The following tables show the amount of each
substance which must be dissolved in water to obtain a liquid of definite
solidifying point. The data relating to alcohol were obtained by Pictet,
and those for calcium chloride by Pickering. The latter are materially
different from figures given by other investigators, and perhaps it would
be safer to make due allowance for this difference. In Germany the
Acetylene Association advocates a 17 per cent. solution of calcium
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