Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
IMPURITIES IN CALCIUM CARBIDE.--The calcium carbide manufactured at the
present time, even when of the best quality commercially obtainable, is
by no means a chemically pure substance; it contains a large number of
foreign bodies, some of which evolve gas on treatment with water. To a
considerable extent this statement will probably always remain true in
the future; for in order to make absolutely pure carbide it would be
necessary for the manufacturer to obtain and employ perfectly pure lime,
carbon, and electrodes in an electric furnace which did not suffer attack
during the passage of a powerful current, or he would have to devise some
process for simultaneously or subsequently removing from his carbide
those impurities which were derived from his impure raw materials or from
the walls of his furnace--and either of these processes would increase
the cost of the finished article to a degree that could hardly be borne.
Beside the impurities thus inevitably arising from the calcium carbide
decomposed, however, other impurities may be added to acetylene by the
action of a badly designed generator or one working on a wrong system of
construction; and therefore it may be said at once that the crude gas
coming from the generating plant is seldom fit for immediate consumption,
while if it be required for the illumination of occupied rooms, it must
invariably be submitted to a rigorous method of chemical purification.
IMPURITIES OF ACETYLENE.--Combining together what may be termed the
carbide impurities and the generator impurities in crude acetylene, the
foreign bodies are partly gaseous, partly liquid, and partly solid. They
may render the gas dangerous from the point of view of possible
explosions; they, or the products derived from them on combustion, may be
harmful to health if inspired, injurious to the fittings and decorations
of rooms, objectionable at the burner orifices by determining, or
assisting in, the formation of solid growths which distort the flame and
so reduce its illuminating power; they may give trouble in the pipes by
condensing from the state of vapour in bends and dips, or by depositing,
if they are already solid, in angles, &c., and so causing stoppages; or
they may be merely harmful economically by acting as diluents to the
acetylene and, by having little or no illuminating value of themselves,
causing the gas to emit less light than it should per unit of volume
consumed, more particularly, of course, when the acetylene is not burnt
under the mantle. Also, not being acetylene, or isomeric therewith, they
require, even if they are combustible, a different proportion of oxygen
for their perfect combustion; and a good acetylene jet is only calculated
to attract precisely that quantity of air to the flame which a gas having
the constitution C_2H_2 demands. It will be apparent without argument
that a proper system of purification is one that is competent to remove
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