Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
have much to do with their production; for the proportion of the total
phosphorus and sulphur found in the crude gas which exists as "compounds"
tends to be greater as the generating plant yields a higher temperature.
It should be noted that ammonia and sulphuretted hydrogen have one
property in common which sharply distinguishes them from the sulphur
"compounds," and from all the phosphorus compounds, including phosphine.
Ammonia and sulphuretted hydrogen are both very soluble in water, the
latter more particularly in the lime-water of an active acetylene
generator; while all the other bodies referred to are completely
insoluble. It follows, therefore, that a proper washing of the crude gas
in water should suffice to remove all the ammonia and sulphuretted
hydrogen from the acetylene; and as a matter of fact those generators in
which the gas is evolved in presence of a large excess of water, and in
which it has to bubble through such water, yield an acetylene practically
free from ammonia, and containing nearly all the sulphur which it does
contain in the state of "compounds." It must also be remembered that
chemical processes which are perfectly suited to the extraction of
sulphuretted hydrogen and phosphine are not necessarily adapted for the
removal of the other phosphorus and sulphur compounds.
WASHERS.--In designing a washer for the extraction of ammonia and
sulphuretted hydrogen it is necessary to see that the gas is brought into
most intimate contact with the liquid, while yet no more pressure than
can possibly be avoided is lost. Subdivision of the gas stream may be
effected by fitting the mouth of the inlet-pipe with a rose having a
large number of very small holes some appreciable distance apart, or by
bending the pipe to a horizontal position and drilling it on its upper
surface with numbers of small holes. Another method is to force the gas
to travel under a series of partitions extending just below the water-
level, forming the lower edges of those partitions either perfectly
horizontal or with small notches like the teeth of a saw. One volume of
pure water only absorbs about three volumes of sulphuretted hydrogen at
atmospheric temperatures, but takes up some 600 volumes of gaseous
ammonia; and as ammonia always accompanies the sulphuretted hydrogen, the
latter may be said to be absorbed in the washer by a solution of ammonia,
a liquid in which sulphuretted hydrogen is much more soluble. Therefore,
since water only dissolves about an equal volume of acetylene, the liquid
in the washer will continue to extract ammonia and sulphuretted hydrogen
long after it is saturated with the hydrocarbon. For this reason,
_i.e._, to avoid waste of acetylene by dissolution in the clean
water of the washer, the plan is sometimes adopted of introducing water
to the generator through the washer, so that practically the carbide is
always attacked by a liquid saturated with acetylene. Provided the liquid
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