Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
It will be observed that both heratol and frankoline are powerfully acid,
whence it follows they are capable of extracting any ammonia that may
enter the purifier; but for the same reason they are liable to act
corrosively upon any metallic vessel in which they are placed, and they
therefore require to be held in earthenware or enamelled receivers. But
since they are not liquid, the casing of the purifier can be safely
constructed of steel or cast iron. Puratylene also removes ammonia by
virtue of the calcium chloride in it. Acagine would probably pass the
ammonia; but this is no real objection, as the latter can be extracted by
a preliminary washing in water. Heratol changes, somewhat obscurely, in
colour as it becomes spent, its original orange tint, due to the chromic
acid, altering to a dirty green, characteristic of the reduced salts of
chromium oxide. Frankoline has been asserted to be capable of
regeneration or revivification, _i.e._, that when spent it may be
rendered fit for further service by being exposed to the air for a time,
as is done with gas oxide; this, however, may be true to some extent with
the essential constituents of frankoline, but the process is not
available with the commercial solid product. Of all these materials,
heratol is the most complete purifier of acetylene, removing phosphorus
and sulphur most rapidly and thoroughly, and not appreciably diminishing
in speed or efficiency until its chromic acid is practically quite used
up. On the other hand, heratol does act upon pure acetylene to some
extent; so that purifiers containing it should be small in size and
frequently recharged. In one of his experiments Keppeler found that 13
per cent. of the chromic acid in heratol was wasted by reacting with
acetylene. As this waste of chromic acid involves also a corresponding
loss of gas, small purifiers are preferable, because at any moment they
only contain a small quantity of material capable of attacking the
acetylene itself. Frankoline is very efficacious as regards the
phosphorus, but it does not wholly extract the sulphur, leaving,
according to Keppeler, from 0.13 to 0.20 gramme of the latter in every
cubic metre of the gas. It does not attack acetylene itself; and if,
owing to its free hydrochloric acid, it adds any acid vapours to the
purified gas, these vapours may be easily removed by a subsequent passage
through a vessel containing lime or a carbide drier. Both being
essentially bleaching-powder, acagine and puratylene are alike in
removing phosphorus to a satisfactory degree; but they leave some sulphur
behind. Acagine evidently attacks acetylene to a slight extent, as
Keppeler has found 0.2 gramme of chlorine per cubic metre in the issuing
gas.
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