Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
These figures are of great practical significance. They indicate that a
mixture of acetylene and air becomes explosive (_i.e._, will explode
if a light is applied to it) when only 3.35 per cent. of the mixture is
acetylene, while a similar mixture of coal-gas and air is not explosive
until the coal-gas reaches 7.9 per cent. of the mixture. And again, air
may be added to coal-gas, and it does not become explosive until the
coal-gas is reduced to 19.1 per cent. of the mixture, while, on the
contrary, if air is added to acetylene, the mixture becomes explosive as
soon as the acetylene has fallen to 52.3 per cent. Hence the immense
importance of taking precautions to avoid, on the one hand, the escape of
acetylene into the air of a room, and, on the other hand, the admixture
of air with the acetylene in any vessel containing it or any pipe through
which it passes. These precautions are far more essential with acetylene
than with coal-gas. The table shows further how great is the danger of
explosion if benzene, benzoline, or other similar highly volatile
hydrocarbons [Footnote: The nomenclature of the different volatile
spirits is apt to be very confusing. "Benzene" is the proper name for the
most volatile hydrocarbon derived from coal-tar, whose formula is C_6H_6.
Commercially, benzene is often known as "benzol" or "benzole"; but it
would be generally advantageous if those latter words were only used to
mean imperfectly rectified benzene, _i.e._, mixtures of benzene with
toluene, &c., such as are more explicitly understood by the terms "90.s
benzol" and "50.s benzol." "Gasoline," "carburine," "petroleum ether,"
"benzine," "benzoline," "petrol," and "petroleum spirit" all refer to
more or less volatile (the most volatile being mentioned first) and more
or less thoroughly rectified products obtained from petroleum. They are
mixtures of different hydrocarbons, the greater part of them having the
general chemical formula C_nH_2n+2 where n = 5 or more. None of them is a
definite chemical compound as is benzene; when n = 5 only the product is
pentane. These hydrocarbons are known to chemists as "paraffins,"
"naphthenes" being occasionally met with; while a certain proportion of
unsaturated hydrocarbons is also present in most petroleum spirits. The
hydrocarbons of coal-tar are "aromatic hydrocarbons," their generic
formula being C_nH_2^n-6, where n is never less than 6.] are allowed to
vaporise in a room in which a light may be introduced. Less of the vapour
of these hydrocarbons than of acetylene in the air of a room brings the
mixture to the lower explosive limit, and therewith subjects it to the
risk of explosion. This tact militates strongly against the use of such
hydrocarbons within a house, or against the use of air-gas, which, as
explained in Chapter I., is air more or less saturated with the vapour of
volatile hydrocarbons. Conversely, a combustible gas, such as acetylene,
may be safely "carburetted" by these hydrocarbons in a properly
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account