Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Turning to the other end of the scale of solubility, the most valuable
liquids for serving as seals of gasholders, &c., are readily discernible.
Far superior to all others is a saturated solution of calcium chloride,
and this should be selected as the confining liquid whenever it is
important to avoid dissolution of acetylene in the liquid as far as may
be. Brine comes next in order of merit for this purpose, but it is
objectionable on account of its corrosive action on metals. Olive oil
should, according to Fuchs and Schiff, be of service where a saline
liquid is undesirable; mineral oil seems useless. Were they concordant,
the figures for milk of lime would be particularly useful, because this
material is naturally the confining liquid in the generating chambers of
carbide-to-water apparatus, and because the temperature of the liquid
rises through the heat evolved during the generation of the gas
(_vide_ Chapters II. and III.). It will be seen that these figures
would afford a means of calculating the maximum possible loss of gas by
dissolution when a known volume of sludge is run off from a carbide-to-
water generator at about any possible temperature.
According to Garelli and Falciola, the depression in the freezing-point
of water caused by the saturation of that liquid with acetylene is 0.08°
C., the corresponding figure for benzene in place of water being 1.40° C.
These figures indicate that 100 parts by weight of water should dissolve
0.1118 part by weight of acetylene at 0° C., and that 100 parts of
benzene should dissolve about 0.687 part of acetylene at 5° C. In other
words, 100 volumes of water at the freezing-point should dissolve 95
volumes of acetylene, and 100 volumes of benzene dissolve some 653
volumes of the gas. The figure calculated for water in this way is lower
than that which might be expected from the direct determinations at other
temperatures already referred to; that for benzene may be compared with
Berthelot's value of 400 volumes at 18° C. Other measurements of the
solubility of acetylene in water at 0° C. have given the figure 0.1162
per cent. by weight.
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