Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The heat evolved by the decomposition of the acetylene by the formation
of the hydrochloric acid in the last equation is then propagated amongst
the rest of the gaseous mixture, accelerating the action, and causing the
acetylene to react with the chlorine to form more hydrochloric acid and
free carbon thus;
C_2H_2 + Cl_2 = 2HCl + C_2.
It is evident that these results do not altogether explain the mechanism
of the reactions involved. Possibly the formation of substitution
products and the consequent occurrence of an explosion is brought about
by some foreign substance which acts as a catalytic agent. Such substance
may conceivably be one of the impurities in crude acetylene, or the solid
matter of a bleaching-powder purifying material. The experiments at least
indicate the direction in which safety may be sought when bleaching-
powder is employed to purify the crude gas, viz., dilution of the powder
with an inert material, absence of air from the gas, and avoidance of
bright sunlight in the place where a spent purifier is being emptied.
Unfortunately Nieuwland did not investigate the action on acetylene of
hypochlorites, which are presumably the active ingredients in bleaching-
powder. As will appear in due course, processes have been devised and
patented to eliminate all danger from the reaction between acetylene and
chlorine for the purpose of making tetrachlorethane in quantity.
Acetylene combines with hydrogen in the presence of platinum black, and
ethylene and then ethane result. It was hoped at one time that this
reaction would lead to the manufacture of alcohol from acetylene being
achieved on a commercial basis; but it was found that it did not proceed
with sufficient smoothness for the process to succeed, and a number of
higher or condensation products were formed at the same time. It has been
shown by Erdmann that the cost of production of alcohol from acetylene
through this reaction must prove prohibitive, and he has indicated
another reaction which he considered more promising. This is the
conversion of acetylene by means of dilute sulphuric acid (3 volumes of
concentrated acid to 7 volumes of water), preferably in the presence of
mercuric oxide, to acetaldehyde. The yield, however, was not
satisfactory, and the process does not appear to have passed beyond the
laboratory stage.
Public-domain text, read in full here on John Shaqi.
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