Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
When suitable precautions are not taken to remove the heat liberated in
an acetylene apparatus, the temperature of the calcium carbide
occasionally rises to a remarkable degree. Investigating this point, Caro
has studied the phenomena of heat production in a "dipping" generator--
_i.e._, an apparatus in which a cage of carbide is alternately
immersed in and lifted out of a vessel containing water. Using a
generator designed to supply five burners, he has found a maximum
recording thermometer placed in the gas space of the apparatus to give
readings generally between 60° and 100° C.; but in two tests out of ten
he obtained temperatures of about 160° C. To determine the actual
temperature of the calcium carbide itself, he scattered amongst the
carbide charge fragments of different fusible metallic alloys which were
known to melt or soften at certain different temperatures. In all his ten
tests the alloys melting at 120° C. were fused completely; in two tests
other alloys melting at 216° and 240° C. showed signs of fusion; and in
one test an alloy melting at 280° C. began to soften. Working with an
experimental apparatus constructed on the "dripping" principle--
_i.e._, a generator in which water is allowed to fall in single
drops or as a fine stream upon a mass of carbide--with the deliberate
object of ascertaining the highest temperatures capable of production
when calcium carbide is decomposed in this particular fashion, and
employing for the measurement of the heat a Le Chatelier thermo-couple,
with its sensitive wires lying among the carbide lumps, Lewes has
observed a maximum temperature of 674° C. to be reached in 19 minutes
when water was dripped upon 227 grammes of carbide at a speed of about 8
grammes per minute. In other experiments he used a laboratory apparatus
designed upon the "dipping" principle, and found maximum temperatures, in
four different trials, of 703°, 734°, 754°, and 807° C., which were
reached in periods of time ranging from 12 to 17 minutes. Even allowing
for the greater delicacy of the instrument adopted by Lewes for measuring
the temperature in comparison with the device employed by Caro, there
still remains an astonishing difference between Caro's maximum of 280°
and Lewes' maximum of 807° C. The explanation of this discrepancy is to
be inferred from what has just been said. The generator used by Caro was
properly made of metal, was quite small in size, was properly designed
with some skill to prevent overheating as much as possible, and was
worked at the speed for which it was intended--in a word, it was as good
an apparatus as could be made of this particular type. Lewes' generator
was simply a piece of glass and metal, in which provisions to avoid
overheating were absent; and therefore the wide difference between the
temperatures noted does not suggest any inaccuracy of observation or
experiment, but shows what can be done to assist in the dissipation of
heat by careful arrangement of parts.
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