Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
which comes to the same thing. Putting the matter in another shape, it
may be said that the reaction between calcium carbide and water is
exothermic, evolving either 14.0 or 29.1 calories according as the
byproduct is calcium oxide or solid calcium hydroxide; and therefore
either reaction proceeds without external assistance in the cold. The
reaction between carbide and slaked lime, however, is endothermic,
absorbing 1.1 calories; and therefore it requires external assistance
(presence of an elevated temperature) to start it, or continuous
introduction of heat (as from the reaction between the rest of the
carbide present and the water) to cause it to proceed. Of itself, and
were it not for the disadvantages attending the production of a
temperature remotely approaching 400° C. in an acetylene generator, which
disadvantages will be explained in the following paragraphs, there is no
particular reason why reaction (3) should not be permitted to occur, for
it involves (theoretically) no loss of acetylene, and no waste of calcium
carbide. Only one specific feature of the reaction has to be remembered,
and due practical allowance made for it. The reaction represented by
equation (2) proceeds almost instantaneously when the calcium carbide is
of ordinarily good quality, and the acetylene resulting therefrom is
wholly generated within a very few minutes. Equation (3), on the
contrary, consumes much time for its completion, and the gas
corresponding with it is evolved at a gradually diminishing speed which
may cause the reaction to continue for hours--a circumstance that may be
highly inconvenient or quite immaterial according to the design of the
apparatus. When, however, it is desired to construct an automatic
acetylene generator, _i.e._, an apparatus in which the quantity of
gas liberated has to be controlled to suit the requirements of any
indefinite number of burners in use on different occasions, equation (3)
becomes a very important factor in the case. To determine the normal
reaction (No. 2) of an acetylene generator, 64 parts by weight of calcium
carbide must react with 36 parts of water to yield 26 parts by weight of
acetylene, and apparently both carbide and water are entirely consumed;
but if opportunity is given for the occurrence of reaction (3), another
64 parts by weight of carbide may be attacked, without the addition of
any more water, producing, inevitably, another 26 parts of acetylene. If,
then, water is in chemical excess in the generator, all the calcium
carbide present will be decomposed according to equation (2), and the
action will take place without delay; after a few minutes' interval the
whole of the acetylene capable of liberation will have been evolved, and
nothing further can possibly happen until another charge of carbide is
inserted in the apparatus. If, on the other hand, calcium carbide is in
chemical excess in the generator, all the water run in will be consumed
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