Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
according to equation (2), and this action will again take place without
delay; but unless the temperature of the residual carbide has been kept
well below 400° C., a further evolution of gas will occur which will not
cease for an indeterminate period of time, and which, by strict theory,
given the necessary conditions, might continue until a second volume of
acetylene equal to that liberated at first had been set free. In practice
this phenomenon of a secondary production of gas, which is known as
"after-generation," is regularly met with in all generators where the
carbide is in excess of the water added; but the amount of acetylene so
evolved rarely exceeds one-quarter or one-third of the main make. The
actual amount evolved and the rate of evolution depend, not merely upon
the quantity of undecomposed carbide still remaining in contact with the
damp lime, but also upon the rapidity with which carbide naturally
decomposes in presence of liquid water, and the size of the lumps. Where
"after-generation" is caused by the ascent of water vapour round lumps of
carbide, the volume of gas produced in a given interval of time is
largely governed by the temperature prevailing and the shape of the
apparatus. It is evident that even copious "after-generation" is a matter
of no consequence in any generator provided with a holder to store the
gas, assuming that by some trustworthy device the addition of water is
stopped by the time that the holder is two-thirds or three-quarters full.
In the absence of a holder, or if the holder fitted is too small to serve
its proper purpose, "aftergeneration" is extremely troublesome and
sometimes dangerous, but a full discussion of this subject must be
postponed to the next chapter.
Public-domain text, read in full here on John Shaqi.
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