Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
Equation (5) shows that 4 volumes of acetylene combine with 10 volumes of
oxygen to produce 8 volumes of carbon dioxide and 4 of water vapour;
while equation (6) indicates that 4 volumes of benzene combine with 30
volumes of oxygen to yield 24 volumes of carbon dioxide and 12 of water
vapour. Two parts by volume of acetylene therefore require 5 parts by
volume of oxygen for perfect combustion, whereas two parts by volume of
benzene need 15--_i.e._, exactly three times as much. In order to
work satisfactorily, and to develop the maximum of illuminating power
from any kind of gas consumed, a gas-burner has to be designed with
considerable skill so as to attract to the base of the flame precisely
that volume of air which contains the quantity of oxygen necessary to
insure complete combustion, for an excess of air in a flame is only less
objectionable than a deficiency thereof. If, then, an acetylene burner is
properly constructed, as most modern ones are, it draws into the flame
air corresponding with two and a half volumes of oxygen for every one
volume of acetylene passing from the jets; whereas if it were intended
for the combustion of benzene vapour it would have to attract three times
that quantity. Since any flame supplied with too little air tends to emit
free carbon or soot, it follows that any well-made acetylene burner
delivering a gas containing benzene vapour will yield a more or lens
smoky flame according to the proportion of benzene in the acetylene.
Moreover, at ordinary temperatures benzene is a liquid, for it boils at
81° C., and although, as was explained above in the case of water, it is
capable of remaining in the state of vapour far below its boiling-point
so long as it is suspended in a sufficiency of some permanent gas like
acetylene, if the proportion of vapour in the gas at any given
temperature exceeds a certain amount the excess will be precipitated in
the liquid form; while as the temperature falls the proportion of vapour
which can be retained in a given volume of gas also diminishes to a
noteworthy extent. Should any liquid, be it water or benzene, or any
other substance, separate from the acetylene under the influence of cold
while the gas is passing through pipes, the liquid will run downwards to
the lowest points in those pipes; and unless due precautions are taken,
by the insertion of draw-off cocks, collecting wells, or the like, to
withdraw the deposited water or other liquid, it will accumulate in all
bends, angles, and dips till the pipes are partly or completely sealed
against the passage of gas, and the lights will either "jump" or be
extinguished altogether. In the specific case of an acetylene generator
this trouble is very likely to arise, even when the gas is not heated
sufficiently during evolution for polymerisation to occur and benzene or
other liquid hydrocarbons to be formed, because any excess of water
present in the decomposing vessel is liable to be vaporised by the heat
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