Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
of the reaction--as already stated it is desirable that water shall be so
vaporised--and will remain safely vaporised as long as the pipes are kept
warm inside or near the generator; but directly the pipes pass away from
the hot generator the cooling action of the air begins, and some liquid
water will be immediately produced. Like the phenomenon of after-
generation, this equally inevitable phenomenon of water condensation will
be either an inconvenience or source of positive danger, or will be a
matter of no consequence whatever, simply as the whole acetylene
installation, including the service-pipes, is ignorantly or intelligently
built.
As long as nothing but pure polymerisation happens to the acetylene, as
long, that is to say, as it is merely converted into other hydrocarbons
also having the general formula C_(2n)H_(2n), no harm will be done to the
gas as regards illuminating power, for benzene burns with a still more
luminous flame than acetylene itself; nor will any injury result to the
gas if it is required for combustion in heating or cooking stoves beyond
the fact that the burners, luminous or atmospheric, will be delivering a
material for the consumption of which they are not properly designed. But
if the temperature should rise much above the point at which benzene is
the most conspicuous product of polymerisation, other far more
complicated changes occur, and harmful effects may be produced in two
separate ways. Some of the new hydrocarbons formed may interact to yield
a mixture of one or more other hydrocarbons containing a higher
proportion of carbon than that which is present in acetylene and benzene,
together with a corresponding proportion of free hydrogen; the former
will probably be either liquids or solids, while the latter burns with a
perfectly non-luminous flame. Thus the quantity of gas evolved from the
carbide and passed into the holder is less than it should be, owing to
the condensation of its non-gaseous constituents. To quote an instance of
this, Haber has found 15 litres of acetylene to be reduced in volume to
10 litres when the gas was heated to 638° C. By other changes, some
"saturated hydrocarbons," _i.e._, bodies having the general formula
C_nH_(2n+2), of which methane or marsh-gas, CH_4 is the best known, may
be produced; and those all possess lower illuminating powers than
acetylene. In two of those experiments already described, where Lewes
observed maximum temperatures ranging from 703° to 807° C., samples of
the gas which issued when the heat was greatest were submitted to
chemical analysis, and their illuminating powers were determined. The
figures he gives are as follows:
I. II.
Per Cent. Per Cent.
Acetylene 70.0 69.7
Saturated hydrocarbons 11.3 11.4
Hydrogen 18.7 18.9
_____ _____
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account