Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
EFFECT OF HIGH TEMPERATURES ON GENERATORS.--As the temperature amongst
the carbide in any generator in which water is not present in large
excess may easily reach 200° C. or upwards, no material ought to be
employed in the construction of such generators which is not competent to
withstand a considerable amount of heat in perfect safety. The ordinary
varieties of soft solder applied with the bitt in all kinds of light
metal-work usually melt, according to their composition, at about 180°
C.; and therefore this method of making joints is only suitable for
objects that are never raised appreciably in temperature above the
boiling-point of water. No joint in an acetylene generator, the partial
or complete failure of which would radically affect the behaviour of the
apparatus, by permitting the charges of carbide and of water to come into
contact at an abnormal rate of speed, by allowing the acetylene to escape
directly through the crack into the atmosphere, or by enabling the water
to run out of the seal of any vessel containing gas so as to set up a
free communication between that vessel and the air, ought ever to be made
of soft solder--every joint of this character should be constructed
either by riveting, by bolting, or by doubly folding the metal sheets.
Apparently, a joint constantly immersed in water on one side cannot rise
in temperature above the boiling-point of the liquid, even when its other
side is heated strongly; but since, even if a generator is not charged
with naturally hard water, its fluid contents soon become "hard" by
dissolution of lime, there is always a liability to the deposition of
water scale over the joint. Such water scale is a very bad heat
conductor, as is seen in steam boilers, so that a seam coated with an
exceedingly thin layer of scale, and heated sharply on one side, will
rise above the boiling-point of water even if the liquid on its opposite
side is ice-cold. For a while the film of scale may be quite water-tight,
but after it has been heated by contact with the hot metal several times
it becomes brittle and cracks without warning. But there is a more
important reason for avoiding the use of plumbers' solder. It might seem
that as the natural hard, protective skin of the metal is liable to be
injured or removed by the bending or by the drilling or punching which
precedes the insertion of the rivets or studs, an application of soft
solder to such a joint should be advantageous. This is not true because
of the influence of galvanic action. As all soft solders consist largely
of lead, if a joint is soldered, a "galvanic couple" of lead and iron, or
of lead and zinc (when the apparatus is built of galvanised steel), is
exposed to the liquid bathing it; and since in both cases the lead is
highly electro-negative to the iron or zinc, it is the iron or zinc which
suffers attack, assuming the liquid to possess any corrosive properties
whatever. Galvanised iron which has been injured during the joint-making
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