Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
GENERATION AT LOW TEMPERATURES.--In all that has been said hitherto about
the reaction between calcium carbide and water being instantaneous, it
has been assumed that the two substances are brought together at or about
the usual temperature of an occupied room, _i.e._, 15 degrees C. If,
however, the temperature is materially lower than this, the speed of the
reaction falls off, until at -5 degrees C., supposing the water still to
remain liquid, evolution of acetylene practically ceases. Even at the
freezing-point of pure water gas is produced but slowly; and if a lump of
carbide is thrown on to a block of ice, decomposition proceeds so gently
that the liberated acetylene may be ignited to form a kind of torch,
while heat is generated with insufficient rapidity to cause the carbide
to sink into the block. This fact has very important bearings upon the
manipulation of an acetylene generator in winter time. It is evident that
unless precautions are taken those portions of an apparatus which contain
water are liable to freeze on a cold night; because, even if the
generator has been at work producing gas (and consequently evolving heat)
till late in the evening, the surplus heat stored in the plant may escape
into the atmosphere long before more acetylene has to be made, and
obviously while frost is still reigning in the neighbourhood. If the
water freezes in the water store, in the pipes leading therefrom, in the
holder seal, or in the actual decomposing chamber, a fresh batch of gas
is either totally incapable of production, because the water cannot be
brought into contact with the calcium carbide in the apparatus, or it can
only be generated with excessive slowness because the carbide introduced
falls on to solid ice. Theoretically, too, there is a possibility that
some portion of the apparatus--a pipe in particular--may be burst by the
freezing, owing to the irresistible force with which water expands when
it changes into the solid condition. Probably this last contingency,
clearly accompanied as it would be by grave risk, is somewhat remote, all
the plant being constructed of elastic material; but in practice even a
simple interference with the functions of a generator by freezing,
ideally of no special moment, is highly dangerous, because of the great
likelihood that hurried and wholly improper attempts to thaw it will be
made by the attendant. As it has been well known for many years that the
solidifying point of water can be lowered to almost any degree below
normal freezing by dissolving in it certain salts in definite
proportions, one of the first methods suggested for preventing the
formation of ice in an acetylene generator was to employ such a salt,
using, in fact, for the decomposition of the carbide some saline solution
which remains liquid below the minimum night temperature of the winter
season. Such a process, however, has proved unsuitable for the purpose in
view; and the explanation of that fact is found in what has just been
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