Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The decomposition which with perfect chemical accuracy has been stated to
occur quantitatively between 36 parts by weight, of water and 64 parts of
calcium carbide scarcely ever takes place in so simple a fashion in an
actual generator. Owing to the heat developed when carbide is in excess,
about half the water is converted into vapour; and so the reaction
proceeds in two stages: half the water added reacting with the carbide as
a liquid, the other half, in a state of vapour, afterwards reacting
similarly, [Footnote: This secondary reaction is manifestly only another
variety of the phenomenon known as "after-generation" (cf. _ante_).
After-generation is possible between calcium carbide and mechanically
damp slaked lime, between carbide and damp gas, or between carbide and
calcium hydroxide, as opportunity shall serve. In all cases the carbide
must be in excess.] or hardly reacting at all, as the case may be.
Suppose a vessel, A B, somewhat cylindrical in shape, is charged with
carbide, and that water is admitted at the end called A. Suppose now (1)
that the exit for gas is at the opposite end, B. As the lumps near A are
attacked by half the liquid introduced, while the other half is changed
into steam, a current, of acetylene and water vapour travels over the
charge lying between the decomposing spot and the end B. During its
passage the second half of the water, as vapour, reacts with the excess
of carbide, the first make of acetylene being dried, and more gas being
produced. Thus a second quantity of heat is developed, equal by theory to
that previously evolved; but a second elevation in temperature, far more
serious, and far less under control, than the former also occurs; and
this is easily sufficient to determine some of those undesirable effects
already described. Digressing for a moment, it may be admitted that the
desiccation of the acetylene produced in this manner is beneficial, even
necessary; but the advantages of drying the gas at this period of its
treatment are outweighed by the concomitant disadvantages and by the
later inevitable remoistening thereof. Suppose now (2) that both the
water inlet and the gas exit of the carbide cylinder are at the same end,
A. Again half the added water, as liquid, reacts with the carbide it
first encounters, but the hot stream of damp gas is not permitted to
travel over the rest of the lumps extending towards B: it is forced to
return upon its steps, leaving B practically untouched. The gas
accordingly escapes from the cylinder at A still loaded with water
vapour, and for a given weight of water introduced much less acetylene is
evolved than in the former case. The gas, too, needs drying somewhere
else in the plant; but these defects are preferable to the apparent
superiority of the first process because overheating is, or can be, more
thoroughly guarded against.
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