Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
ACTION OF WATER-TO-CARBIDE GENERATORS.--Having by one or other of the
means described obtained a supply of water intermittent in character, it
remains to be considered how that supply may be made to approach the
carbide in the generator. Actual acetylene apparatus are so various in
kind, and merge from one type to another by such small differences, that
it is somewhat difficult to classify them in a simple and intelligible
fashion. However, it may be said that water-to-carbide generators,
_i.e._, such as employ water as the moving material, may be divided
into four categories: (F^1) water is allowed to fall as single drops or
as a fine stream upon a mass of carbide--this being the "drip" generator;
(F^2) a mass of water is made to rise round and then recede from a
stationary vessel containing carbide--this being essentially identical in
all respects save the mechanical one with the "dip" or "dipping"
generator shown in A^2, Fig. 1; (F^3) a supply of water is permitted to
rise round, or to flow upon, a stationary mass of carbide without ever
receding from the position it has once assumed--this being the "contact"
generator; and (F^4) a supply of water is admitted to a subdivided charge
of carbide in such proportion that each quantity admitted is in chemical
excess of the carbide it attacks. With the exception of F^2, which has
already been illustrated as A^2 Fig. 1, or as B^1 in Fig. 2, these
methods of decomposing carbide are represented in Figs. 4 and 5. It will
be observed that whereas in both F^1 and F^3 the liberated acetylene
passes off at the top of the apparatus, or rather from the top of the
non-subdivided charge of carbide, in F^1 the water enters at the top, and
in F^3 it enters at the bottom. Thus it happens that the mixture of
acetylene and steam, which is produced at the spot where the primary
chemical reaction is taking place, has to travel through the entire mass
of carbide present in a generator belonging to type F^3, while in F^1 the
damp gas flows directly to the exit pipe without having to penetrate the
lumps of solid. Both F^1 and F^3 exhibit after-generation caused by a
reaction between the liquid water mechanically clinging to the mass of
spent lime and the excess of carbide to an approximately equal extent;
but for the reason just mentioned, after-generation due to a reaction
between the vaporised water accompanying the acetylene first evolved and
the excess of carbide is more noticeable in F^3 than in F^1; and it is
precisely this latter description of after-generation which leads to
overheating of the most ungovernable kind. Naturally both F^1 and F^3 can
be fitted with water jackets, as is indicated by the dotted lines in the
second sketch; but unless the generating chamber in quite small and the
evolution of gas quite slow, the cooling action of the jacket will not
prove sufficient. As the water in F^1 and F^3 is not capable of backward
motion, the decomposing chambers cannot be employed as displacement
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