Alchemy: Ancient and Modern: Being a Brief Account of the Alchemistic Doctrines, and Their Relations, to Mysticism on the One Hand, and to Recent Discoveries in Physical Science on the Other Hand; Together with Some Particulars Regarding the Lives and Teachings of the Most Noted AlchemistsRedgrove, H. Stanley (Herbert Stanley)
Religion
Alchemy: Ancient and Modern: Being a Brief Account of the Alchemistic Doctrines, and Their Relations, to Mysticism on the One Hand, and to Recent Discoveries in Physical Science on the Other Hand; Together with Some Particulars Regarding the Lives and Teachings of the Most Noted Alchemists
Redgrove, H. Stanley (Herbert Stanley)
Alchemy -- History
§ =89.= Radium salts give off three distinct sorts of rays, referred to
by the Greek letters α, β, γ. The α-rays have been shown to consist of
electrically charged (positive) particles, with a mass approximately
equal to that of four hydrogen atoms; they are slightly deviated by a
magnetic field, and do not possess great penetrative power. The β-rays
are similar to the kathode rays, and consist of (negative) electrons;
they are strongly deviated by a magnetic field, in a direction opposite
to that in which the α-particles are deviated, and possess medium
penetrative power, passing for the most part through a thin sheet of
metal. The γ-rays resemble X-rays; they possess great penetrative
power, and are not deviated by a magnetic field. The difference in the
effect of the magnetic field on these rays, and the difference in their
penetrative power, led to their detection and allows of their separate
examination. Radium salts emit also an emanation, which tends to become
occluded in the solid salt, but can be conveniently liberated by
dissolving the salt in water, or by heating it. The emanation exhibits
the characteristic properties of a gas, it obeys Boyle’s Law (_i.e._,
its volume varies inversely with its pressure), and it can be condensed
to a liquid at low temperatures; its density as determined by the
diffusion method is about 100. Attempts to prepare chemical compounds of
the emanation have failed, and in this respect it resembles the rare
gases of the atmosphere--helium, neon, argon, krypton, and xenon--whence
it is probable that its molecules are monatomic, so that a density of
100 would give its atomic weight as 200.[105] As can be seen from the
table on pp. 106, 107, an atomic weight of about 220 corresponds to a
position in the column containing the rare gases in the periodic system.
That the emanation actually has an atomic weight of these dimensions was
confirmed by further experiments carried out by the late Sir William
Ramsay and Dr. R. W. Gray.[106] These chemists determined the density of
the emanation by actually weighing minute quantities of known volume of
the substance, sealed up in small capillary tubes, a specially
sensitive balance being employed. Values for the density varying from
108 to 113½, corresponding to values for the atomic weight varying from
216 to 227, were thereby obtained. Sir William Ramsay, therefore,
considered that there could no longer be any doubt that the emanation
was one of the elements of the group of chemically inert gases. He
proposed to call it _Niton_, and, for reasons which we shall note later,
considered that in all probability it had an atomic weight of about
222½.
[105] This follows from Avogadro’s Hypothesis, see § 76.
[106] Sir WILLIAM RAMSAY and Dr. R. W. GRAY: “La densité de
l’émanation du radium,” _Comptes Rendus hebdomadaires des Séances de
l’Académie des Sciences_, vol. cvi. (1910), pp. 126 _et seq._
The Disintegration of the Radium Atom.
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