An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Chemical properties.~ Chemically iodine is quite similar to chlorine and
bromine, but is still less active than bromine. It combines directly
with many elements at ordinary temperatures. At elevated temperatures it
combines with hydrogen, but the reaction is reversible and the compound
formed is quite easily decomposed. Both chlorine and bromine displace it
from its salts:
KI + Br = KBr + I,
KI + Cl = KCl + I.
When even minute traces of iodine are added to thin starch paste a very
intense blue color develops, and this reaction forms a delicate test for
iodine. Iodine is extensively used in medicine, especially in the form
of a tincture. It is also largely used in the preparation of dyes and
organic drugs, iodoform, a substance used as an antiseptic, has the
formula CHI_{3}.
~Hydriodic acid (HI).~ This acid cannot be prepared in pure condition by
the action of sulphuric acid upon an iodide, since the hydriodic acid
set free is oxidized by the sulphuric acid just as in the case of
hydrobromic acid, but to a much greater extent. It can be prepared in
exactly the same way as hydrobromic acid, iodine being substituted for
bromine. It can also be prepared by passing hydrosulphuric acid into
water in which iodine is suspended. The equation is
H_{2}S + 2I = 2HI + S.
The hydriodic acid formed in this way dissolves in the water.
~Properties and uses.~ Hydriodic acid resembles the corresponding acids of
chlorine and bromine in physical properties, being a strongly fuming,
colorless gas, readily soluble in water. Under standard conditions 1
volume of water dissolves about 460 volumes of the gas. It is, however,
more unstable than either hydrochloric or hydrobromic acids, and on
exposure to the air it gradually decomposes in accordance with the
equation
2HI + O = H_{2}O + 2I.
Owing to the slight affinity between iodine and hydrogen the acid easily
gives up its hydrogen and is therefore a strong reducing agent. This is
seen in its action on sulphuric acid.
The salts of hydriodic acid, the iodides, are, in general, similar to
the chlorides and bromides. Potassium iodide (KI) is the most familiar
of the iodides and is largely used in medicine.
~Oxygen compounds.~ Iodine has a much greater affinity for oxygen
than has either chlorine or bromine. When heated with nitric
acid it forms a stable oxide (I_{2}O_{5}). Salts of iodic acid
(HIO_{3}) and periodic acid (HIO_{4}) are easily prepared, and
the free acids are much more stable than the corresponding
acids of the other members of this family.
GAY-LUSSAC'S LAW OF VOLUMES
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