An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Uses of zinc.~ The metal has many familiar uses. Rolled into sheets, it
is used as a lining for vessels which are to contain water. As a thin
film upon the surface of iron (galvanized iron) it protects the iron
from rust. Iron is usually galvanized by dipping it into a bath of
melted zinc, but electrical methods are also employed. Zinc plates are
used in many forms of electrical batteries. In the laboratory zinc is
used in the preparation of hydrogen, and in the form of zinc dust as a
reducing agent.
One of the largest uses of zinc is in the manufacture of alloys. Brass,
an alloy of zinc and copper, is the most important of these; German
silver, consisting of copper, zinc, and nickel, has many uses; various
bronzes, coin metals, and bearing metals also contain zinc. Its ability
to alloy with silver finds application in the separation of silver from
lead (see silver).
~Compounds of zinc.~ In general, the compounds of zinc are similar in
formula and appearance to those of magnesium, but in other properties
they often differ markedly. A number of them have value in commercial
ways.
~Zinc oxide~ (_zinc white_) (ZnO). Zinc oxide occurs in impure form in
nature, being colored red by manganese and iron compounds. It can be
prepared just like magnesium oxide, but is more often made by burning
the metal.
Zinc oxide is a pure white powder which becomes yellow on heating and
regains its white color when cold. It is much used as a white pigment in
paints, under the name of zinc white, and has the advantage over white
lead in that it is not changed in color by sulphur compounds, while lead
turns black. It is also used in the manufacture of rubber goods.
~Commercial preparation of zinc oxide.~ Commercially it is often
made from franklinite in the following way. The franklinite is
mixed with coal and heated to a high temperature in a furnace,
by which process the zinc is set free and converted into vapor.
As the vapor leaves the furnace through a conduit it meets a
current of air and takes fire in it, forming zinc oxide. The
oxide passes on and is filtered from the air through canvas
bags, which allow the air to pass but retain the oxide. It is
thus made by burning the metal, though the metal is not
actually isolated in the process.
~Soluble salts.~ The soluble salts of zinc can be made by dissolving the
metal or the oxide in the appropriate acid. They are all somewhat
poisonous. The sulphate and chloride are the most familiar.
~Zinc sulphate~ (_white vitriol_) (ZnSO_{4}.7H_{2}O). This salt is readily
crystallized from strong solutions in transparent colorless crystals. It
is prepared commercially by careful roasting of the sulphide:
ZnS + 4O = ZnSO_{4}.
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