An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Platinic chloride (PtCl_{4}).~ Platinic chloride is an orange-colored,
soluble compound made by heating chloroplatinic acid in a current of
chlorine. If hydrochloric acid is added to a solution of the substance,
the two combine, forming chloroplatinic acid (H_{2}PtCl_{6}):
2HCl + PtCl_{4} = H_{2}PtCl_{6}.
The potassium and ammonium salts of this acid are nearly insoluble in
water and alcohol. The acid is therefore used as a reagent to
precipitate potassium in analytical work. With potassium chloride the
equation is
2KCl + H_{2}PtCl_{6} = K_{2}PtCl_{6} + 2HCl.
~Other metals of the family.~ The other members of the family
have few applications. Iridium is used in the form of a
platinum alloy, since the alloy is much harder than pure
platinum and is even less fusible. This alloy is sometimes used
to point gold pens. Osmium tetroxide (OsO_{4}) is a very
volatile liquid and is used under the name of osmic acid as a
stain for sections in microscopy.
GOLD
~Occurrence.~ Gold has been found in many localities, the most famous
being South Africa, Australia, Russia, and the United States. In this
country it is found in Alaska and in nearly half of the states of the
union, notably in California, Colorado, and Nevada. It is usually found
in the native condition, frequently alloyed with silver; in combination
it is sometimes found as telluride (AuTe_{2}), and in a few other
compounds.
~Mining.~ Native gold occurs in the form of small grains or larger nuggets
in the sands of old rivers, or imbedded in quartz veins in rocks. In the
first case it is obtained in crude form by placer mining. The sand
containing the gold is shaken or stirred in troughs of running waters
called sluices. This sweeps away the sand but allows the heavier gold to
sink to the bottom of the sluice. Sometimes the sand containing the gold
is washed away from its natural location into the sluices by powerful
streams of water delivered under pressure from pipes. This is called
hydraulic mining. In vein mining the gold-bearing quartz is mined from
the veins, stamped into fine powder in stamping mills, and the gold
extracted by one of the processes to be described.
~Extraction.~ 1. _Amalgamation process._ In the amalgamation process the
powder containing the gold is washed over a series of copper plates
whose surfaces have been amalgamated with mercury. The gold sticks to
the mercury or alloys with it, and after a time the gold and mercury are
scraped off and the mixture is distilled. The mercury distills off and
the gold is left in the retort ready for refining.
2. _Chlorination process._ When gold occurs along with metallic
sulphides it is often extracted by chlorination. The ore is first
roasted, and is then moistened and treated with chlorine. This dissolves
the gold but not the metallic oxides:
Au + 3Cl = AuCl_{3}.
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