An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Definitions.~ When a substance disappears in a liquid in such a way as to
thoroughly mix with it and to be lost to sight as an individual body,
the resulting liquid is called a _solution_. The liquid in which the
substance dissolves is called the _solvent_, while the dissolved
substance is called the _solute_.
~Classes of solutions.~ Matter in any one of its physical states may
dissolve in a liquid, so that we may have solutions of gases, of
liquids, and of solids. Solutions of liquids in liquids are not often
mentioned in the following pages, but the other two classes will become
very familiar in the course of our study, and deserve special attention.
SOLUTION OF GASES IN LIQUIDS
[Illustration: Fig. 30]
It has already been stated that oxygen, hydrogen, and nitrogen are
slightly soluble in water. Accurate study has led to the conclusion that
all gases are soluble to some extent not only in water but in many other
liquids. The amount of a gas which will dissolve in a liquid depends
upon a number of conditions, and these can best be understood by
supposing a vessel B (Fig. 30), to be filled with the gas and inverted
over the liquid. Under these circumstances the gas cannot escape or
become mixed with another gas.
~Circumstances affecting the solubility of gases.~ A number of
circumstances affect the solubility of a gas in a liquid.
1. _Nature of the gas._ Other conditions being equal, each gas has its
own peculiar solubility, just as it has its own special taste or odor.
The solubility of gases varies between wide limits, as will be seen from
the following table, but as a rule a given volume of a liquid will not
dissolve more than two or three times its own volume of a gas.
_Solubility of Gases in Water_
1 l. of water at 760 mm. pressure and at 0 deg. will dissolve:
Ammonia 1148.00 l.
Hydrochloric acid 503.00
Sulphur dioxide 79.79
Carbon dioxide 1.80
Oxygen 41.14 cc.
Hydrogen 21.15
Nitrogen 20.03
In the case of very soluble gases, such as the first three in the table,
it is probable that chemical combination between the liquid and the gas
takes place.
2. _Nature of the liquid._ The character of the liquid has much
influence upon the solubility of a gas. Water, alcohol, and ether have
each its own peculiar solvent power. From the solubility of a gas in
water, no prediction can be made as to its solubility in other liquids.
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