An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Characteristics of salts.~ (1) From the definition of a salt it will be
seen that there is no element or group of elements which characterize
salts. (2) Salts as a class have no peculiar taste. (3) In the absence
of all other substances they are without action on indicators. (4) When
dissolved in water they form two kinds of ions.
~Heat of neutralization.~ If neutralization is due to the union
of hydrogen ions with hydroxyl ions, and nothing more, it
follows that when a given weight of water is formed in
neutralization, the heat set free should always be the same, no
matter from what acid and base the two kinds of ions have been
supplied. Careful experiments have shown that this is the case,
provided no other reactions take place at the same time. When
18g. of water are formed in neutralization, 13,700 cal. of heat
are set free. This is represented in the equations
Na^{+}, OH^{-} + H^{+}, Cl^{-}
= Na^{+}, Cl^{-} + H_{2}O + 13,700 cal.
K^{+}, OH^{-} + H^{+}, NO_{3}^{-}
= K^{+}, NO_{3}^{-} + H_{2}O + 13,700 cal.
Ca^{++}, (OH)_{2}^{--} + H_{2}^{++}, SO_{4}^{--}
= Ca^{++}, SO_{4}^{--} + 2H_{2}O + 2 x 13,700 cal.
~Neutralization a quantitative act.~ Since neutralization is a definite
chemical act, each acid will require a perfectly definite weight of each
base for its neutralization. For example, a given weight of sulphuric
acid will always require a definite weight of sodium hydroxide, in
accordance with the equation
H_{2}, SO_{4} + 2Na, OH = Na_{2}, SO_{4} + 2H_{2}O.
~Determination of the ratio in neutralization.~ The quantities of
acid and base required in neutralization may be determined in
the following way. Dilute solutions of the two substances are
prepared, the sulphuric acid being placed in one of the
burettes (Fig. 34) and the sodium hydroxide in the other. The
levels of the two liquids are then brought to the zero marks of
the burettes by means of the stopcocks. A measured volume of
the acid is drawn off into a beaker, a few drops of litmus
solution added, and the sodium hydroxide is run in drop by drop
until the red litmus just turns blue. The volume of the sodium
hydroxide consumed is then noted. If the concentrations of the
two solutions are known, it is easy to calculate what weight of
sodium hydroxide is required to neutralize a given weight of
sulphuric acid. By evaporating the neutralized solution to
dryness, the weight of the sodium sulphate formed can be
determined directly. Experiment shows that the weights are
always in accordance with the equation in the preceding
paragraph.
[Illustration: Fig. 34]
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