The drying of the substance was a great inconvenience in the Voltaic
pile, and the inventor proposed, as a remedy for this, to station the
metallic plates at a greater distance from one another, and to fill up
the cells or intervals between them with a saline solution. Mr.
Cruickshank, an English chemist at Woolwich, improved this
construction.—His _trough_ as it is called, is made thus.—
Get a wooden trough, made of hard baked mahogany, about thirty inches
long, and four or five wide and deep.—On the inside let there be cut in
the sides and bottom, and at equal distances from one another, as many
grooves, as the number of plates required to be put into the trough;—the
grooves of a size to admit the plates. The plates are to be cemented[18]
separately to each of the grooves, so that no fluid can pass from one
cell to another. In this instrument the plates are constructed by
soldering a plate of zinc to one of copper. The zinc, or which is the
same thing, the spelter of the shops, should be melted in a vessel which
exposes but a small surface to the action of the air, otherwise it would
absorb oxygen so rapidly as to be converted into the flowers of
zinc.—The melted metal should be poured as soon as possible into a mould
of the proper size, made of stone or brass.—It is not necessary that the
plates of copper should be more than one tenth of the thickness of those
of zinc.
The two plates are commonly soldered, not through their whole extent,
but about one fourth of an inch from the edge; so that at the edge their
union may be complete.
Care must be taken that all the plates be cemented to the trough in the
same direction; so as to have the copper side of every plate opposite to
the zinc side of the next.
The liquid employed to fill up the cells between the plates, is formed
by diluting muriatic acid with water, in the proportion of one ounce of
the former to a pint of the latter. When the trough is not in use, it
should be emptied of this solution (which may be preserved for
subsequent experiments, unless saturated with the metals) and then
rinsed clean with fresh water.
This construction is preferable to the Voltaic pile, for experiments in
which it is necessary to have the Galvanic action for a length of time.
But for occasional experiments the pile is more convenient; as the
trough, if suffered to remain long without the fluid, is apt to crack
and separate the cement from the plates, which renders it necessary to
cement them again.
Public-domain text, read in full here on John Shaqi.
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