1. Hydrogen gas, mixed with a small portion of oxygen and ammonia, is
somehow disengaged at the wire communicating with the silver extremity
of the pile; and this effect is equally produced, whatever the nature of
the metallic wire may be, provided the fluid operated upon be _water_.
2. When metallic solutions are used, the same wire which separates the
hydrogen gas, revives the metallic calx, and deposits it at its
extremity, in its pure metallic state; in this case no hydrogen is
disengaged. The wire employed for this purpose may be of any metal.
3. Of the earthy solutions, only those of magnesia and argill are
decomposed by the wire: a circumstance which strongly favours the
production of ammonia.
CHAP. VI.
_Experiments on the deflagration of Metals by the Galvanic Pile._
The pile with which these experiments were made consisted of thirty-six
plates of silver, and an equal number of zinc ones, between which were
interposed disks of flannel, moistened with a solution of the muriate of
ammonia.—Each plate had a diameter of ten inches, or contained 78.58
square inches;—consequently the whole surface of silver in the pile,
reckoning only one side, was 2828.57 square inches, and that of zinc the
same.
With this instrument, in December 1801, gold, silver, copper, tin, lead
and zinc were deflagrated with surprising facility. The gold burned with
a vivid white light, inclining a little to blue, and deposited an oxyd
of a deep purplish-brown colour.—The silver gave a vivid flame of a
greenish hue, and extremely brilliant. Its oxyd was of a blackish
colour. The copper presented phenomena similar to those which attended
the gold.—Lead gave a very vivid light, of a dilute bluish purple.—The
tin afforded a light similar to that of the gold, but burnt with much
less energy; probably because the leaves were thicker. The zinc gave a
blueish white flame, which was edged, at the moment of contact, with
red. It was more difficult to inflame than any of the preceding metals,
but the leaves were likewise much thicker. The oxyds of the four last
metals were not examined.
Water was poured upon the upper plate of the pile, so as to form a
_standing pool_; and several pieces of the same kind of metals with
those before experimented upon, were presented to the plate through this
aqueous medium, and were deflagrated. They afforded a flame of the same
colour as when they were brought to the bare plate.—A vapour was
sometimes perceptible immediately after the deflagration, and was
supposed to arise from a portion of water converted into steam by the
intense heat.
It is very remarkable that the shocks taken from this pile, which
produced such astonishing effects upon metals, could be received with
but very trifling inconvenience, through the human body.
Public-domain text, read in full here on John Shaqi.
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