An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
342. New Theory of Chemistry. We have seen that heat lies at the
basis of chemical as well as of physical changes. By the loss of
heat, or perhaps by the change of potential into kinetic energy,
in a nebulous parent mass, planets were formed, capable of
supporting living organisms. Heat changes solids to liquids, and
liquids to gases; it resolves compounds, or it aids chemical
union. In every chemical combination heat is developed; in every
case of dissociation heat is absorbed. Properly written, every
equation should be: a + b = c + heat; e.g. 2 H + 0 = H2O + heat;
or, c - a = b - heat; e.g. H2O - 2 H = 0 - heat. Another
illustration is the combination of C and O, and the dissociation
of CO2, as given on page 82. C + O2 = CO2 + energy. CO2 - O2 = C
- energy. In fact, there are indications that the present theory
of atoms and molecules of matter, as the foundation of chemistry,
will at no distant day give place to a theory of chemistry based
on the forms of energy, of which heat is a manifestation.
Chapter, LXII.
GAS VOLUMES AND WEIGHTS.
343. Oxygen.
Experiment 134.--Weigh accurately, using delicate balances, 5 g.
KClO3, and mix with the crystals 1 or 2 g. of pure powdered MnO2.
Put the mixture into a t.t. with a tight-fitting cork and
delivery-tube, and invert over the water-pan, to collect the gas,
a flask of at least one and a half liters' capacity, filled with
water. Apply heat, and, without rejecting any of the gas, collect
it as long as any will separate.
Then press the flask down into the water till the level in the
flask is the same as that outside, and remove the flask, leaving
in the bottom all the water that is not displaced. Weigh the
flask with the water it contains; then completely fill it with
water and weigh again.
Subtract the first weight from the second, and the result will
evidently be the weight of water that occupies the same volume as
the O collected. This weight, if expressed in grams, represents
approximately the number of cubic centimeters of water,--since 1
cc. of water weighs lg,--or the number of cubic centimeters of O.
At the time the experiment is performed the temperature should be
noted with a centigrade thermometer, and the atmospheric pressure
with a barometer graduated to millimeters.
Suppose that we have obtained 1450 cc. of O, that the temperature
is 27 degrees, and the pressure 758 mm.; we wish to find the
volume and the weight of the gas at 0 degrees and 760 mm.
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