An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Much earthy material--gangue--containing silica and silicates is
always found with iron ores. These are infusible, and something
must be added to render them fusible. CaO forms with SiO2 just
the flux needed. See page 132. Ca0 + Si02 = ? Which of these is
the basic, and which the acidic compound? CaO results from
heating CaCO3; hence the latter is employed instead of the
former. In what case would Si02 be used as the flux?
Into the blast furnace are put, in alternate layers, the fuel,
the flux, and the ore. The fire, once kindled, is kept burning
for months or years. Hot air is driven in through the tuyeres
(tweers). O unites with C of the fuel, forming CO2 and CO. The C
also reduces the ore. Fe2O3 + 3 C = ? CO accomplishes the same
thing. 3 CO + Fe2O3 = ? The intense heat fuses CaO and SiO2 to a
silicate which, with other impurities, forms a slag; this, rising
to the surface of the molten mass, is drawn off. The iron is
melted, falls in drops to the bottom, and is drawn off into sand
molds. See Figure 47. This is pig-iron. It contains as
impurities, C, Si, S, P, Mn, etc. If too much S or P is present
in an ore, it is worthless. This is why the abundant mineral FeS2
cannot be used as a source of iron. From the top of the furnace
N, CO, CO2, H2O, etc., escape. These gases are used to heat the
air which is forced through the tuyeres, and to make steam in
boilers.
267. Steel.--The manufacture of steel and wrought-iron consists
in removing most of the impurities from pig-iron. It will be seen
that the most common compounds of C, S, Si, and P, are their
oxides, and these are for the most part gases. Hence these
elements are removed by oxidation.
Bessemer steel is prepared by melting pig-iron and blowing hot
air through it. A converter (Fig. 48) lined with siliceous sand,
and holding several tons, is partially filled with the molten
metal; blasts of hot air are driven into it, and the C and other
impurities, together with a little of the Fe, are oxidized. The
exact moment when the process has gone far enough, and most of
the impurities have been removed, is indicated by the appearance
of the escaping flame. It usually takes from five to ten minutes.
The blast is then stopped, and the metal has about the
composition of wrought-iron; it contains some uncombined O. A
white pig-iron (spiegeleisen), which contains a known quantity of
C and of Mn, is at once added. Mn removes part of the extra O,
and, though it remains, does not injure the metal. The C is
"dissolved" by the Fe, which is then run into molds (ingots).
This process, the Bessemer, invented in 1856, has revolutionized
steel manufacture. No less than ten tons of iron have been
converted into steel, in five minutes, in a single converter.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account