An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
295. General Considerations.--Inorganic chemistry is the
chemistry of minerals, or unorganized bodies. Organic chemistry
was formerly defined as the chemistry of the compounds found in
plants and animals; but of late it has taken a much wider range,
and is now defined as the chemistry of the C compounds, since C
is the nucleus around which other elements centre, and with which
they combine to form the organic substances. New organic
compounds are constantly being discovered and synthesized, so
that nearly 100,000 are now known. The molecule of organic matter
is often very complex, sometimes containing hundreds of atoms.
In organic as in inorganic chemistry, atoms are bound together by
chemical affinity, though it was formerly supposed that an
additional or vital force was instrumental in forming organic
compounds. For this reason none of these substances, it was
thought, could be built up in the laboratory, although many had
been analyzed. In 1828 the first organic compound, urea, was
artificially prepared, and since then thousands have been
synthesized. They are not necessarily manufactured from organic
products, but can be made from mineral matter.
296. Molecular Differences.--Molecules may differ in three ways:
(1) In the kind of atoms they contain. Compare CO2 and CS2. (2)
In the number of atoms. Compare CO and CO2. (3) In the
arrangement of atoms, i.e. the molecular structure. Ethyl alcohol
and methyl ether have the same number of the same elements,
C2H6O, but their molecular structure is not the same, and hence
their properties differ.
Qualitative analysis shows what elements enter into a compound;
quantitative analysis shows the proportion of these elements;
structural analysis exhibits molecular structure, and is the
branch to which organic chemists are now giving particular
attention. `
A specialist often works for years to synthesize a series of
compounds in the laboratory.
297. Sources.--Some organic products are now made in a purer and
cheaper form than Nature herself prepares them. Alizarine, the
coloring principle of madder, was until lately obtained only from
the root of the madder plant; now it is almost wholly
manufactured from coal-tar, and the manufactured article serves
its purpose much better than the native product. Ten million
dollars' worth is annually made, and Holland, the home of the
plant, is giving up madder culture. Artificial naphthol-scarlet
is abolishing the culture of the cochineal insect. Indigo has
also been synthesized. Certain compounds have been predicted from
a theoretical molecular structure, then made, and afterwards
found to exist in plants. Others are made that have no known
natural existence. The source of a large number of artificial
organic products is coal-tar, from bituminous coal. Saccharine, a
compound with two hundred and eighty times the sweetening power
of sugar, is one of its latest products. Wood, bones, and various
fermentable liquids are other sources of organic compounds.
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