An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
In his analyses of air Dalton made use of the old nitric oxide method.
In 1802 this led to an interesting discovery. If in a tube .3 of an inch
wide he mixed 100 parts of common air with 36 parts of nitric oxide, the
oxygen of the air combined with the nitric oxide, and a residue of 79
parts of atmospheric nitrogen remained. And if he mixed 100 parts of
common air with 72 of nitric oxide, but in a wide vessel over water (in
which conditions the combination is more quickly effected), the oxygen
of the air again combined with the nitric oxide and a residue of 79
parts of nitrogen again resulted. But in the last experiment, if less
than 72 parts of nitric oxide be employed, there will be a residue of
oxygen as well as nitrogen; and if more than 72, there will be a residue
of nitric oxide in addition to the nitrogen. In the words of Dalton,
"oxygen may combine with a certain portion of nitrous gas [as he called
nitric oxide], or with twice that portion, but with no intermediate
portion."
Naturally these experimental facts were to be explained in terms of the
ultimate particles of which the various gases are composed. In the
following year Dalton gave graphic representation to his idea of the
atomic constitution of chemical elements and compounds.
( ) Hydrogen
(|) Nitrogen
(·) Oxygen
(*) Carbon
(|) (·) Nitric oxide
(·) (|) (·) Nitrous oxide
(·) (*) (·) Carbonic acid
Much against Dalton's will his method of indicating chemical elements
and their combinations had to yield to a method introduced by the great
Swedish chemist Berzelius. In 1837 Dalton wrote: "Berzelius's symbols
are horrifying: a young student in chemistry might as soon learn Hebrew
as make himself acquainted with them. They appear like a chaos of atoms
... and to equally perplex the adepts of science, to discourage the
learner, as well as to cloud the beauty and simplicity of the Atomic
Theory."
Public-domain text, read in full here on John Shaqi.
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