An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
"Without such a theory," says Sir Henry Roscoe, "modern chemistry would
be a chaos; with it, order reigns supreme, and every apparently
contradictory discovery only marks out more distinctly the value and
importance of Dalton's work." In 1826 Sir Humphry Davy recognized
Dalton's services to science in the following terms: "Finding that in
certain compounds of gaseous bodies the same elements always combined
in the same proportions, and that when there was more than one
combination the quantity of the elements always had a constant
relation,--such as 1 to 2, or 1 to 3, or 1 to 4,--he explained this fact
on the Newtonian doctrine of indivisible atoms; and contended that, the
relative weight of one atom to that of any other atom being known, its
proportions or weight in all its combinations might be ascertained, thus
making the statics of chemistry depend upon simple questions in
subtraction or multiplication and enabling the student to deduce an
immense number of facts from a few well-authenticated experimental
results. Mr. Dalton's permanent reputation will rest upon his having
discovered a simple principle universally applicable to the facts of
chemistry, in fixing the proportions in which bodies combine, and thus
laying the foundation for future labors respecting the sublime and
transcendental parts of the science of corpuscular motion. His merits in
this respect resemble those of Kepler in astronomy."
In 1808 Dalton's atomic theory received striking confirmation through
the investigations of the French scientist Gay-Lussac, who showed that
gases, under similar circumstances of temperature and pressure, always
combine in simple proportions by _volume_ when they act on one another,
and that when the result of the union is a gas, its volume also is in a
simple ratio to the volumes of its components. One of Dalton's friends
summed up the result of Gay-Lussac's research in this simple fashion:
"His paper is on the combination of gases. He finds that all unite in
equal bulks, or two bulks of one to one of another, or three bulks of
one to one of another." When Dalton had investigated the relative
weights with which elements combine, he had found no simple arithmetical
relationship between atomic weight and atomic weight. When two or more
compounds of the same elements are formed, Dalton found, however, as we
have seen, that the proportion of the element added to form the second
or third compound is a multiple by weight of the first quantity.
Gay-Lussac now showed that gases, "in whatever proportions they may
combine, always give rise to compounds whose elements by volume are
multiples of each other."
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