An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
In the following year Davy reported other chemical changes produced by
electricity; he had succeeded in decomposing the fixed alkalis and
discovering the elements potassium and sodium. To analyze a small piece
of pure potash slightly moist from the atmosphere, he had placed it on
an insulated platinum disk connected with the negative side of a voltaic
battery. A platinum wire connected with the positive side was brought in
contact with the upper surface of the alkali. "The potash began to fuse
at both its points of electrization." At the lower (negative) surface
small globules having a high metallic luster like quicksilver appeared,
some of which burned with explosion and flame while others remained and
became tarnished. When Davy saw these globules of a hitherto unknown
metal, he danced about the laboratory in ecstasy and for some time was
too much excited to continue his experiments.
After recovering from a very severe illness, owing in the judgment of
some to overapplication to experimental science, and in his own judgment
to a visit to Newgate Prison with the purpose of improving its sanitary
condition, Davy made an investigation of the alkaline earths. He failed
in his endeavor to obtain from these sources pure metals, but he gave
names to barium, strontium, calcium, and magnesium, conjecturing that
the alkaline earths were, like potash and soda, metallic oxides. In
addition Davy anticipated the isolation of silicon, aluminium, and
zirconium. No doubt what gave special zest to his study of the alkalis
was the hope of overthrowing the doctrine of French chemists that oxygen
was the essential element of every acid. Lavoisier had given it, indeed,
the name oxygen (acid-producer) on that supposition. Davy showed,
however, that this element is a constituent of many alkalis.
In 1810 he advanced his controversy by explaining the nature of
chlorine. Discovered long before by the indefatigable Scheele, it bore
at the beginning of the nineteenth century the name oxymuriatic acid.
Davy proved that it contained neither oxygen nor muriatic (hydrochloric)
acid (though, as we know, it forms, with hydrogen, muriatic acid). He
gave the name _chlorine_ because of the color of the gas (χλωρός, pale
green). Davy studied later the compounds of fluorine, and though unable
to isolate the element, conjectured its likeness to chlorine.
He lectured before the Dublin Society in 1810, and again in the
following year; on the occasion of his second visit receiving the degree
of LL.D. from Trinity College. He was knighted in the spring of 1812,
and was married to a handsome, intellectual, and wealthy lady. He was
appointed Honorary Professor of Chemistry at the Royal Institution. His
new independence gave him full liberty to pursue his scientific
interests. Toward the close of 1812 he writes to Lady Davy:--
Public-domain text, read in full here on John Shaqi.
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