An Introduction to the History of ScienceLibby, Walter
History
An Introduction to the History of Science
Libby, Walter
Science -- History
Before Rutherford, Mme. Curie, and others especially interested in
radioactive substances, assumed that atoms are far different from the
massy, hard, impenetrable particles that Newton took for granted, Sir J.
J. Thomson and his school were studying the constitution of the atom
from another standpoint but with somewhat similar results. This great
physicist had proved that cathode rays are composed not of negatively
charged molecules, as had been supposed, but of much smaller particles
or corpuscles. Wherever, as in the vacuum tube, these electrons appear,
the presence of positively charged particles can also be demonstrated.
It is manifest that the atom, instead of being the ultimate unit of
matter, is a system of positively and negatively charged particles.
Rutherford in the main concurred in this view, though differing from Sir
J. J. Thomson as to the arrangement of corpuscles within the atom. Let
it suffice here to state that Rutherford assumes that the greater mass
of the atom consists of negatively charged particles rotating about a
positive nucleus. The surrounding electrons render the atom electrically
neutral.
This corpuscular theory of matter may throw light on the laws of
chemical combination. The so-called chemical affinity between two atoms
of such and such valencies, which Davy and others since his time had
regarded as essentially an electrical phenomenon, seems now to admit of
more definite interpretation. Each atom is negatively or positively
charged according to the addition or subtraction of electrons. Chemical
composition takes place between atoms the charges of which are of
opposite sign, and valency depends on the number of unit charges of
electricity. Moreover, the electrical theory of matter lends support to
the hypothesis that there is a fundamental unitary element underlying
all the so-called elements. The fact that elements fall into groups and
that their chemical properties vary with their atomic weights long ago
suggested this assumption of a primitive matter, _protyl_, from which
all other substances were derived. In the light of the corpuscular
theory as well as of the transformation theory it seems possible that
the helium atom and the negative corpuscle will offer a clue to the
genesis of the elements.
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