An Introductory Course of Quantitative Chemical Analysis: With Explanatory NotesTalbot, Henry Paul
Science
An Introductory Course of Quantitative Chemical Analysis: With Explanatory Notes
Talbot, Henry Paul
Chemistry, Analytic -- Quantitative
Stannous chloride, SnCl_{2}, made by saturating hydrochloric acid (sp.
gr. 1.2) with tin, diluting with an equal volume of water, and adding
a slight excess of acid from time to time. A strip of metallic tin is
kept in the bottle.
A solution of ammonium molybdate is best prepared as follows: Stir
100 grams of molybdic acid (MoO_{3}) into 400 cc. of cold, distilled
water. Add 80 cc. of concentrated ammonium hydroxide (sp. gr. 0.90).
Filter, and pour the filtrate slowly, with constant stirring, into a
mixture of 400 cc. concentrated nitric acid (sp. gr. 1.42) and 600
cc. of water. Add to the mixture about 0.05 gram of microcosmic salt.
Filter, after allowing the whole to stand for 24 hours.
The following data regarding the common acids and aqueous ammonia
are based upon percentages given in the Standard Tables of the
Manufacturing Chemists' Association of the United States [!J.S.C.I.!,
24 (1905), 787-790]. All gravities are taken at 15.5°C. and compared
with water at the same temperature.
Aqueous ammonia (sp. gr. 0.96) contains 9.91 per cent NH_{3} by
weight, and corresponds to a 5.6 N and 5.6 molal solution.
Aqueous ammonia (sp. gr. 0.90) contains 28.52 per cent NH_{3} by
weight, and corresponds to a 5.6 N and 5.6 molal solution.
Hydrochloric acid (sp. gr. 1.12) contains 23.81 per cent HCl by
weight, and corresponds to a 7.3 N and 7.3 molal solution.
Hydrochloric acid (sp. gr. 1.20) contains 39.80 per cent HCl by
weight, and corresponds to a 13.1 N and 13.1 molal solution.
Nitric acid (sp. gr. 1.20) contains 32.25 per cent HNO_{3} by weight,
and corresponds to a 6.1 N and 6.1 molal solution:
Nitric acid (sp. gr. 1.42) contains 69.96 per cent HNO_{3} by weight,
and corresponds to a 15.8 N and 15.8 molal solution.
Sulphuric acid (sp. gr. 1.8354) contains 93.19 per cent H_{2}SO_{4} by
weight, and corresponds to a 34.8 N or 17.4 molal solution.
Sulphuric acid (sp. gr. 1.18) contains 24.74 per cent H_{2}SO_{4} by
weight, and corresponds to a 5.9 N or 2.95 molal solution.
The term !normal! (N), as used above, has the same significance as
in volumetric analyses. The molal solution is assumed to contain one
molecular weight in grams in a liter of solution.
DENSITIES AND VOLUMES OF WATER AT TEMPERATURES FROM 15-30°C.
Temperature Density. Volume.
Centigrade.
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