from the crust and "retanned" in sumach before dyeing, to coat the
fibres with a fresh and more adsorbent gel and so ensure the even and
thorough adsorption of the dyestuff. Mordanting fabrics has a similar
object,--the adsorption of colloidogenic substances which give rise to
an adsorbent gel on the fibre. Unless vegetable-tanned leather is so
much loaded with tan that its specific surface is effectively reduced,
one would similarly expect that vegetable-tanned leather would adsorb
the chrome sol. This, of course, is exactly the case of semi-chrome
leather. If, on the "chemical combination" theory, the vegetable tan
combines with the amino groups and the chrome with carboxyl groups, it
is natural to inquire which groups the dyestuffs combine with. As either
tannage does not interfere with the adsorption of dye, are we to
conclude similarly that tanning and dyeing are fundamentally different
processes?
Those who favour this chemical combination theory, and who offer
equations for the formation of vegetable and of chrome leather, should
likewise suggest an equation for the formation of leather from pelt by
the action of dyestuffs--a practical though hardly an economic process.
The remarks made earlier in this volume (Part I., Section III.) as to
the occurrence of what have been called "irreversible changes"
subsequent to the mutual precipitation of oppositely charged gel and
sol, are equally applicable to the chrome tannages. Chrome tannage was
once thought to embrace such irreversible changes, but the process can
now be "reversed" with ease. The reversibility of the chrome tannage is
an easier proposition than that of vegetable tannage, partly because the
leather is comparatively much less tanned, and partly because the
acidity or alkalinity of the stripping agent may be adjusted, as
desired, without the oxidation trouble. In approaching this question
from the theoretical side one must consider mainly whether to solate the
tanning agent to a positive or to a negative sol. Our imperfect
knowledge of the electrical forces in operation in the chrome tannage is
thus a serious drawback, but the evidence on the whole points to the
precipitation being effected by a negative sol near its isoelectric
point but in faintly acid solution. Hence, we should theoretically
expect that reversion should take place into a negative sol in nearly
neutral or even faintly alkaline solution. Thus, suitable stripping
agents for chrome leather would be the alkali salts of organic acids
(especially if multivalent). Now, Procter and Wilson have recently
accomplished this stripping of chrome leather by the use of such salts.
They approached the question from an empirical and practical point of
view and found that Rochelle salt, sodium citrate, and sodium lactate
would strip the chrome tannage with ease. This important and very
creditable achievement will have great practical and commercial
importance. Procter and Wilson have deliberately and carefully refrained
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