All the figures are percentages of the weight of pelt. As K{2}Cr{2}O7
has a molecular weight of 294, and Na{2}Cr{2}O{7}·2H{2}O a molecular
weight of 298, in practice they may be considered as interchangeable,
weight for weight. The sodium salt is cheaper and more often used. The
corresponding amount of chromic acid, 2CrO{3}, has an equivalent weight
of 200, hence any weight of dichromate may in practice be substituted by
two-thirds the weight of commercial chromic acid. Equivalent weights of
commercial sulphuric acid are sometimes used in place of hydrochloric.
The quantity depends upon the strength of the sulphuric acid used.
Aluminium sulphate, Al{2}(SO{4}){3}·18H{2}O (mol. wt. 666), may be
replaced by ordinary potash alum, K{2}SO{4}·Al{2}(SO{4}){3}·24H{2}O
(mol. wt. 948). In practice 7 parts of the former and 10 parts of the
latter may be considered equivalent. It should be remembered that both
these salts are hydrolyzed in solution, and therefore increase slightly
the amount of free acid present. Their presence decreases the amount of
chrome taken up, and as little or no alumina is found in the leather,
there is usually small advantage in their employment. The use of salt is
common but often unnecessary. It is considered desirable in baths of the
acid type to prevent swelling by the excess of acid, and in baths made
up from commercial chromic acid to replace correspondingly that normally
formed from the reaction of dichromate and acid. It is used also in all
baths which are intended to treat pickled goods. Like all electrolytes
its presence decreases the adsorption of chromic acid.
All these conceivable modifications will make good leather, and the
choice of a process often depends largely upon market prices. On the
whole the tendency is to prefer the neutral or acid type, on account of
the greater ease and completeness with which the bath may be exhausted.
Pickled stock may be depickled before tanning, by a bath of salt, mixed
with borax, whitening, or basic alum solutions. It may also be placed
direct in the chroming bath, but the amount of acid thus added with the
goods must be determined and allowed for when making up the bath. No
allowance is usually necessary, however, if the "pickle" consist only of
alum and salt.
The chroming operation is carried out usually in drums or paddles. Drums
are preferable because more concentrated baths may be used; these
solutions penetrate quicker and are easier to exhaust economically. They
are also preferable for hides and heavy skins. Paddles are preferable
where grain is important, and for light skins in which little time is
needed. Small variations in the ratio of chrome to pelt, or in
concentration of liquor, have little influence upon the resulting
leather.
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