In any case, the goods are successively brought into contact with
liquors of increasing strength, as in vegetable tannage, and the liquors
are thus most conveniently exhausted economically. The green goods thus
receive first nearly spent liquor and finish out of fresh strong liquor.
The goods may be, of course, handled from drum to drum, or from pit to
pit, but the modern tendency is to save labour by moving the liquors
instead. Thus in drum tanning the liquor is run out and pumped into the
next drum. In pits air ejectors have proved suitable, not only as lift
pumps, but also as agitators of the liquor in which goods are suspended.
The press system is also used.
=Finishing Operations.=--In nearly all cases the chrome leather has
to be "neutralized" after tanning. This consists in removing the acid
"reversibly adsorbed". This removal is necessary to the finishing
processes, as well as to bring the tanning sol into condition for more
permanent tannage. Neutralization gets rid of soluble chrome salts as
well as free mineral acid, and is the final stage in rendering the
tanning sol less positive, and perhaps even negative. It is brought
about by the use of weak alkalies, of which borax is the easiest and
safest, but not the cheapest. Sodium silicate, phosphate, carbonate, and
bicarbonate have been also used, and a mixture of soda and an ammonium
salt has been suggested by Stiasny. Whitening has also been tried, but
is very slow-acting. Considerable economy in alkali may be effected by a
thorough washing of the leather before using the alkali. If the water be
hard, so much the better, and if warm water be available the process is
hastened. For most leathers it is necessary to remove excess of alkali
just as much as excess of acid, so that a thorough washing in water
generally follows the treatment with alkali. Anything from 1/4 to 3 per
cent. borax (or its equivalent) on the pelt weight may be used, and,
generally speaking, it is better to use solutions as dilute as
practicable in order to avoid local over-neutralization and tender
leather.
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