also the use of warm solutions of the commercial organic acids (lactic,
formic, acetic, butyric, etc.), together with calcium chloride. In place
of the chloride, a salt of the acid may be employed, and the deliming
bath may be regenerated by oxalic acid and used repeatedly. Sometimes
puering is omitted and the desired result obtained by washing in warm
water, nearly deliming with warm solutions of organic acid, washing
again and drenching. Skins are also washed often after drenching.
In tanning chrome goat for glacé the two-bath process is mostly
preferred. This is partly because the sulphur deposited in the reducing
bath assists materially in producing the mellowness and fullness which
are so essential, and partly because a large proportion of skins are
finished in colours. The two-bath process also lends itself to a paddle
tannage, which is necessary for the smooth grain finish. One or two
illustrative processes may be given.
One process presents many points of resemblance to the first process
suggested for willow calf in Section III. (_q.v._). The skins are first
pickled in a paddle with 2 per cent. hydrochloric acid and 10 per cent.
salt, and then pass into the chroming paddle, which contains at first
only 2 per cent. dichromate. Subsequently 4 per cent. dichromate, 3-1/2
per cent. hydrochloric acid, and 5 per cent. salt are added to the
paddle liquor, and the skins paddled until well struck through. After
being horsed overnight the skins are struck out by machine, passed
through a hypo dip if desired, and reduced with 12 per cent. of
thiosulphate and about 5 per cent. of acid. The skins may be left
overnight in the hypo paddle, and the excess of thiosulphate, which is a
feeble alkali, commences the neutralization.
In another process the chroming bath is made up of 5-1/2 per cent.
chromic acid and 6-1/2 per cent. of salt, and to this paddle liquor 2 or
3 per cent. of aluminium sulphate may be added if desired. The reduction
is with 14 per cent. hypo and 7 per cent. hydrochloric acid. A little of
the acid is added to the reducing bath; when the liquor turns milky, the
skins are rapidly inserted, and the rest of the acid gradually added.
In the finishing processes the mechanical operation of "striking" is
very prominent, on account of the necessity of obtaining area and smooth
grain. The skin of goats has rather a tendency to bold grain, and this
enhances the need of striking. Most manufacturers lay great stress upon
thorough neutralization and washing. An important point also is that the
staking should be carried out at the proper condition of dryness. If
either too damp or too dry, the requisite mellow feel is not obtained.
There is, of course, ample scope for variation and ingenuity, and the
following processes for blacks and colours must be taken as broadly
typical.
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