After liming the soaked, softened and plumped stock is washed as
thoroughly as possible. To do this it is necessary to supply repeated
batches of clean cold water. Some manufacturers, however, use the warm
water from the evaporators. Wooden vats or brick pits with arrangements
for agitation, for draining off and for inspection, are used for this
purpose. The agitation may be carried out by means of revolving shafts
or drums with projecting curved spokes or vanes. An American patent
(Hoeveler's glue stock washer) involves the use of a paddle wheel. It is
combined with a settling tank to gather particles of stock. In the
washing the chalk, excess lime, dirt, etc., are quickly removed and a
slow deliming process is commenced. The sediment from the washers and
wash waters has some value in making fertilizers. Deliming cannot be
carried on further than certain limits by water alone. Hence acid is
often added to finish off the process. Hydrochloric acid has the
advantage of forming soluble salts, but if they are not removed
completely their lyotrope influence is to weaken the gelatine. Sulphuric
and sulphurous acids are even cheaper, and the lyotrope influence of
their salts is in the opposite sense. The latter also has the advantage
of destroying sulphides, an important advantage for food gelatines.
Whatever acid is used, however, it is evident that an abundance of pure
cold water is the fundamental requirement of a pure product. It is a
sound maxim in gelatine manufacture to avoid, if at all possible, the
addition of any soluble substance, for it is always present in a more
concentrated state in the finished article. Thus if its solubility be
even moderate, one is likely to attain supersaturation in the "cake"
and consequently a dull product. Further, lyotrope influences can never
strengthen a gel very much, but may and often do weaken it very
considerably. Hence the aim of most manufacturers in the preliminary
treatment is so to delime that a nearly neutral and salt-free product is
obtained. An exception is the case of skin gelatine in which excess of
sulphurous acid is used. This process has for its object not only
deliming and purifying, but also a bleaching action.
In the case of =bone gelatine=, the raw material is such that there are
much longer and more elaborate preparatory processes. This arises from
the fact that about half the bones of animals consists of mineral
matter, chiefly calcium phosphate. Bones, of course, vary in composition
to some extent, and those from younger animals contain distinctly less
of the mineral constituents. Approximately speaking, bones have the
following average composition:--
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