The next stage is the extraction of the mineral matters by acid, for
which purpose hydrochloric acid has proved very suitable, as both
phosphate and carbonate of lime are dissolved by it. The usual
counter-current system of extraction is used [_cp._ Leaching and extract
manufacture, Part I., Section III., p. 35]. The process is methodical
and regular, the acid liquor passing successively through a battery
of six vats in such a manner that the liquor richest in lime salts comes
into contact with the bones most recently charged; the fresh acid thus
acts upon the nearly extracted bones. The hydrochloric acid used is of 8
to 10 per cent. strength (5° to 7° Bé.). Stronger acid is apt to
hydrolyze ("rot") the gelatine, whilst weaker acid takes longer time.
The process takes 8 to 10 days, though up to 14 days is sometimes given,
and, on the other hand, the process has been occasionally reduced to 4
days. The gelatinous matter undissolved has the shape of the original
bone, but is much swollen. When the acid liquor is saturated with lime
salt, the liquor is drawn off from below the vats and sent to the
phosphate precipitation tanks. The phosphate is usually precipitated by
adding just sufficient milk of lime to neutralize the hydrochloric acid.
The precipitated phosphate is then well washed by decantation to remove
calcium chloride. It is then drained, and dried at a low temperature. As
a large bulk of phosphate is obtained it is often filter-pressed and
dried quickly in long revolving chambers through which a current of air
is passed. The phosphate is sometimes also precipitated by ammonia. It
is then more easily washed and dried, and the ammonium chloride is
recovered and may be used to regenerate ammonia, or be sold as a
valuable bye-product. Sometimes the acid liquor is not used for making
precipitated phosphate, but is evaporated with animal charcoal and
silica and then distilled to make phosphorus.
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