The adsorption law indicates that however much colouring matter is
removed from the volume concentration (continuous phase) there must
always be some left. After all that the decolorization processes can do,
there still remains much colour that can only be removed by a chemical
action of the ordinary sense. The amount of colouring matter of this
kind is not large, but it is a deep red-brown, and when the gelatine sol
has been evaporated and dried out the final product, if untreated,
possesses this typical colour, and is known as glue. If, before
gelation, a chemical bleaching action is applied to destroy this
pigment, the product may be then dried out in a nearly colourless
condition and is known as gelatine. Gelatine, therefore, is simply
bleached glue. Many other definitions have been given, and many
elaborate distinctions drawn, but the fact of bleaching is the essential
difference. In these days when gelatine is so valuable, the higher-grade
products are nearly always bleached, and the term "glue" is consequently
more often applied to a lower-grade product, and is sometimes used in a
sense implying this fact.
If it be desired to manufacture gelatine, it is fairly obvious that the
task is lightened by observing the axiom that prevention is better than
cure. If steps are taken to prevent the presence or development of such
colouring matter, a great advantage is attained, for not only is the
problem of bleaching easier, but also quicker and less expensive in
chemicals. The nature of the colouring matters is but imperfectly
investigated, but in the case of skin gelatine the pigment of the hair
roots and epidermis is doubtless one factor. A long liming is said to
assist in its destruction, possibly because this completes the loosening
of epithelial structures and possibly because the alkali causes some
hydrolysis of the pigment. In both skin and bone gelatine sols, however,
there is a considerable tendency to develop the brown colouring matter
typical of glue. This tendency is enhanced by an increase in temperature
and also by the presence of acid or alkali. These facts seem to indicate
that its development is associated with a partial hydrolysis of the
gelatine in some direction. Rideal says this colouring matter is allied
to caramel. In harmony with this is the experience that its development
is greatest in products which have been "burnt," _i.e._ subjected to
unusually high temperature. The practical maxims which arise from these
considerations are fairly obvious and widely known, viz. to conduct the
extraction and evaporation at as low a temperature as possible and in as
neutral a condition as practicable. The temperature is particularly
important during evaporation (see Section VI.).
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account