After the stoving is complete, the product is given a few days under
ordinary atmospheric conditions to permit the reabsorption of moisture
to the usual extent. Enamelled leathers are then grained to develop the
pattern.
REFERENCE.
Bennett, "Manufacture of Leather," p. 380.
PART III.--CHROME LEATHER
SECTION I.--THE NATURE OF CHROME LEATHERS
In these days the manufacture of chrome leather has attained a position
hardly less in importance than that occupied by the ancient method of
tanning by means of the vegetable tanning materials, and large
quantities of hides and skins are now "chrome tanned" after preparatory
processes analogous to those described in connection with vegetable
tannages (Part II., Section II.; and Part II., Section I.).
Chrome leathers are made by tanning pelts with the salts of chromium,
and are typical of what are known as "mineral tannages," in which
inorganic salts are the tanning agents. Tannage with alum and salt (see
Part IV., Section I.) is one of the earliest mineral tannages, but is
now of relatively minor importance. Chrome tanning was first
investigated by Knapp (1858), who experimented with chromic chloride
made "basic" by adding alkali, but his conclusions were unfavourable to
the process. A patent was taken out later by Cavallin in which skins
were to be tanned by treating with potassium dichromate and then with
ferrous sulphate which reduced the former to chromic salts, being itself
converted into ferric salt. The product, which was a combination of
iron-chrome tannage, did not yield a satisfactory commercial leather.
Another patent, taken out in 1879 by Heinzerling, specified the use of
potassium dichromate and alum. This in effect was a combination
chrome-alumina tannage. The alum had its own tanning action and the
dichromate was reduced to chromic salts by the organic matter of the
skin itself and by the greases employed in dressing. The process,
however, was not a commercial success. In 1881 patents were obtained by
Eitner, an Austrian, whose process was a combination chrome and fat
tannage. The chrome was employed as "basic chromium sulphate" made by
adding common soda to a solution of chrome alum until a salt
corresponding to the formula Cr(OH)SO{4} was obtained. Such a solution
is now known to be perfectly satisfactory, but at first it proved
difficult to devise satisfactory finishing processes, and to supplement
the chrome tannage with the fat tannage.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account