Appletons' Popular Science Monthly, April 1900: Vol. 56, Nov. 1899 to April, 1900Various
History
Appletons' Popular Science Monthly, April 1900: Vol. 56, Nov. 1899 to April, 1900
Various
Science -- Periodicals; Technology -- Periodicals
While the investigations of Dalton and of Davy were still incomplete,
other chemists were actively studying the properties of gases and
exploring the fertile border-land between chemistry and physics. In
1805 Gay-Lussac and Humboldt determined the composition of water by
_volume_; in 1808 Gay-Lussac extended these observations, and found
that in all compound gases simple volumetric relations existed; and
in 1811 the entire subject was generalized into Avogadro’s law.
Avogadro showed that equal volumes of gases, compared under equivalent
conditions, must contain equal numbers of molecules, and although the
force of his discovery was not fully appreciated until much later,
it is now recognized as one of the fundamental propositions of both
physics and chemistry. For the first time the distinction between atoms
and molecules was clearly stated, and from the density of a gas the
relative weight of its molecule could be calculated. Avogadro’s law
rounded out and completed the atomic theory, and to its application
much of the advance in organic chemistry is due. Equally striking, but
less far-reaching in its consequences, was the discovery announced by
Dulong and Petit in 1819, when it was shown that the specific heat of
an element was inversely proportional to its atomic weight. Otherwise
stated, this law asserts that the atoms of all the elements have the
same capacity for heat, and an important check upon determinations of
atomic weight was thus provided.
The next twenty years in the history of chemistry were years of
detail rather than of permanent generalizations. The multitudinous
verification of known laws, the development of experimental methods,
especially methods of analysis, the discovery of new elements, the
preparation of numberless new compounds, occupied the attention of most
workers. This period, which may be called the Berzelian period, was
enormously fruitful in results, although but few of the theories then
proposed have survived to the present day. During this period the name
and influence of Berzelius overshadowed all others, and his marvelous
researches, carried out in a laboratory which was hardly more than
a kitchen, were of almost incredible variety. For the crude symbols
of Dalton, Berzelius substituted a system of chemical formulæ which
could be used in chemical equations; in 1818 and 1826 he published
tables of atomic weights, determined with far greater exactness than
ever before; he discovered five new elements and a multitude of
compounds, devised methods of research, and proposed theories which,
though later to be overthrown, for many years dominated chemical
science. His electro-chemical experiments led him to his dualistic
theory of compounds, which interpreted each compound as made up of two
parts--one positive, the other negative. The electro-positive oxides
were basic, the electro-negative groups were acid; chemical affinity
was electrical attraction between the two opposites; chemical union
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