Appletons' Popular Science Monthly, April 1900: Vol. 56, Nov. 1899 to April, 1900Various
History
Appletons' Popular Science Monthly, April 1900: Vol. 56, Nov. 1899 to April, 1900
Various
Science -- Periodicals; Technology -- Periodicals
According to the periodic law, all the properties of the elements are
periodic functions of their atomic weights, varying from substance
to substance in a perfectly regular manner. The elements thus fall
into periods, or octaves, as Newlands called them, of a very striking
character. If, for example, we start with univalent lithium, the next
higher element has a valence of two, the next of three, and then comes
carbon, whose atom is quadrivalent. Following carbon, the combining
power of successive elements decreases until we reach sodium, in which
something like the properties of lithium recur. Above sodium the same
rise goes on to the fourth element higher, silicon, which resembles
carbon, and then follows the regular step-by-step falling away, to end
with chlorine, the last member of the second period. This periodic
rising and falling is characteristic of all the elements, and they were
so tabulated by Mendelejeff as to be perfectly clear, with a clearness
which is not to be given by words. In Mendelejeff’s table certain gaps
appeared, which he ascribed to the existence of undiscovered metals.
For three of these he predicted the properties, starting out from
the properties of their neighbors. This was a rash thing to do, but
the venture has been fully vindicated. In 1875 Lecoq de Boisbandram
discovered gallium, which filled one of the gaps; scandium and
germanium filled the other two later. The predictions of Mendelejeff
were fulfilled; atomic weight, specific gravity, fusibility, the
character of the compounds to be formed, were all foreseen for each
of the three new elements; and, so far as experiment has yet gone,
his anticipations have been perfectly realized. Every good theory is
prophetic; but few generalizations have been so strikingly verified
in this respect as has the periodic law. In spite of some outstanding
difficulties, yet to be explained, the law has served to great
advantage in the classification of the elements, and it has had much to
do with the late revival of inorganic chemistry. The latter branch of
science, long comparatively neglected, has now gained new interest, and
for it, in the near future, a great growth can be prophesied.
The immediate effect of the periodic law was to prove that the
elements are connected with one another by general relations, and so
to stimulate the belief in their possibly common origin. This view has
many upholders, although it is also strongly opposed, but the weight
of argument seems to be in its favor. On philosophic grounds it is at
least more probable than the opposite opinion, which can not account
in any way for the regularities which have been observed. From another
source, partly physical and partly chemical, the theory of the unity
of matter has received strong support, and this statement brings us
to another of the greatest discoveries made during the nineteenth
century--that of the spectroscope and spectrum analysis.
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