Appletons' Popular Science Monthly, January 1900: Vol. 56, November, 1899 to April, 1900Various
Science
Appletons' Popular Science Monthly, January 1900: Vol. 56, November, 1899 to April, 1900
Various
Science -- Periodicals; Technology -- Periodicals
In the light of our experience of the last eight years, it is easy
to identify as electrolysis the effects shown in the accompanying
cuts of buried metals that have been actually subjected to a flow of
electricity. It is not to be inferred that the destructive action here
depicted is universal throughout our towns, but, rather, that the
damage occurs in spots, its rate of progress being dependent upon the
amount of current and the duration of the flow. Dry, sandy soils tend
to keep down the flow of current by interposing a high resistance, so
that in such localities electrolytic effects are not as pronounced
as in wet, loamy soils. In the same way, the character of the pipe
surface--or coating, if there be any--acts as a partial barrier to
check the passage of electricity.
Until recently it was generally supposed that cast iron was not
attacked--at least not rapidly enough to cause alarm. In Brooklyn the
water mains, of very hard, dense, even-grained cast iron, containing
alloyed rather than combined carbon, have not been appreciably
corroded. At Dayton, Ohio, on the other hand, seventy-seven thousand
dollars’ worth of damage has already resulted. One peculiarity of
electrolyzed cast iron is that the original shape is usually retained,
the iron being eaten away and leaving a punky formation of pure or
nearly pure graphite. In such a case a superficial examination detects
nothing wrong, and it requires a mechanical scraping to show that the
strength is not there. For this reason good photographs of cast-iron
electrolysis are somewhat hard to obtain.
[Illustration: LEAD SERVICE PIPE AFTER EIGHT MONTHS’ BURIAL IN
BUILDERS’ SAND. The collapsed appearance of the pipe is due entirely
to the removal of the lead by electrolysis, the bore retaining its
original shape. The dark spot on the upper surface of the pipe is the
point of rupture. One third size.]
The reason for the comparative immunity of cast iron is not as yet
definitely understood. It certainly does not lie particularly in the
asphaltic varnish usually applied, for this varnish affords little or
no protection when used upon wrought iron or other metals. Nor can it
be accounted for by the composition of cast iron itself, inasmuch as a
fractured or brightly scraped surface of cast iron shows approximately
the same symptoms as other metals when acted upon by a given current
for a given time. Whether the iron oxide is the saving feature, or
whether the “skin” due to the process of casting acts as an insulator,
is not yet settled.
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