Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899Various
Religion
Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899
Various
Science -- Periodicals; Technology -- Periodicals
The statement is still current that acetylene attacks copper and
brass, forming an explosive compound. This is not true. Exhaustive
experiments by Moissan and by Gerdes, keeping these and other metals
in contact with acetylene for months at a time, have shown that the
metals were not affected. The conditions under which the explosive
copper acetylide is made in laboratories can not well occur in
generators or gas holders. It has been said that acetylene is very
poisonous; the experiments of many observers, and especially those of
Gréhant, do not confirm this statement. Gréhant experimented on dogs,
causing them to breathe mixtures of acetylene, air, and oxygen, which
always contained 20.8 per cent of oxygen, this being the percentage of
oxygen in pure air. By this device he was able to discriminate between
the poisoning caused by acetylene and suffocation caused by
insufficient oxygen. A mixture containing twenty per cent acetylene
inhaled for thirty-five minutes did not seem to trouble the animal. A
sample of the dog's arterial blood contained ten per cent of
acetylene. A dog which inhaled a mixture containing forty per cent of
acetylene died suddenly after fifty-one minutes, having inhaled one
hundred and twelve litres of the mixture; the arterial blood contained
twenty per cent acetylene. Gréhant proved that acetylene simply
dissolves in the blood plasma, while carbon monoxide forms a compound
with the hæmoglobin of the blood. A dog breathing a similar mixture of
air, oxygen, and illuminating gas containing only one per cent of
carbon monoxide quickly showed convulsive movements, and died after
ten minutes; its blood contained twenty-four per cent of carbon
monoxide. Thus acetylene, while slightly poisonous, is less poisonous
than coal gas, and vastly less than water gas, which contains a high
percentage of carbon monoxide.
A pressure of thirty-nine atmospheres and three quarters at 20° C.
converts acetylene into a liquid weighing one third as much as the
same volume of water, while one cubic foot of the liquid when released
from pressure gives five hundred cubic feet of gas.
Hitherto acetylene is used only as a source of heat or as a source of
light; yet with very cheap carbide it would prove useful in many ways
in chemical industry, and its use would have the most wide-spread
effect on industry and agriculture. For instance, a method of making
alcohol from acetylene is patented abroad, and by another patented
process it is proposed to make sugar from acetylene. With the present
prices of alcohol, sugar, and carbide, these processes have no
commercial value.
Acetylene may be made from the carbide in gas works and delivered to
the consumer through mains like ordinary illuminating gas; or it may
be liquefied at a gas works and delivered to the consumer in the
liquid form under pressure; or the consumer may purchase carbide and
generate acetylene for his own consumption. All three of these methods
are in use.
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