Appletons' Popular Science Monthly, October 1899: Vol. LV, May to October, 1899Various
Philosophy
Appletons' Popular Science Monthly, October 1899: Vol. LV, May to October, 1899
Various
Science -- Periodicals; Technology -- Periodicals
the time nor the wit to become a sound scholar nor a profound
mathematician. But he may, if he understand his privilege aright,
linger for a while in the groves of 'practically useless' knowledge.
He may learn what literature meant in an age when it was concerned
only with the essentials of simplicity; he may read the lessons of
history when history was still separate from political intrigue. And
though he forgets his Greek grammar, though in middle life he can not
construe a page of Virgil, yet he carries away from this irrational
interlude a vague impression of beauty which no other course of
education will ever give him." Even for the schoolmen "a vague
impression of beauty," whatever that may mean, seems rather
unpractical as an educational _ultima Thule_.
=The Purple of Cassius.=--There are few substances in the field of
inorganic chemistry on which so much speculation and actual work has
been expended as the so-called purple of Cassius. A recent article by
Mr. C. L. Reese, in the Chemical News, contains some interesting
information regarding this curious compound. Up to the present time
there have, it seems, been two views held as to its chemical
nature--one that it is a mixture of stannic acid and metallic gold;
the other, that of Berzelius, that it is substantially a chemical
compound of purple gold oxide with the oxides of tin possibly mixed
with an excess of stannic acid. It has seemed very likely that the
substance is a chemical compound of acid character, and that the
solubility in ammonia is due to the formation of a salt, but it has
been found that by oxidation of stannous chloride and by allowing very
dilute solutions of stannic chloride to stand, the "hydrogel" of
stannic acid separated out, which, on the addition of a few drops of
ammonia, liquefied and so became soluble in water, just as the purple
of Cassius does. There can therefore be no salt formation here. Some
comparatively recent work by Richard Zsigmondy, however, seems to have
finally cleared up the chemical nature of this curious substance. Its
formation is explained by assuming that when stannous chloride is
added to a sufficiently dilute solution of gold chloride the latter is
immediately reduced to metallic gold while stannic chloride is formed.
Generally after a few seconds the liquid becomes red, but the purple
is not precipitated for several days, unless it is heated. The gold is
not precipitated as a black powder because the stannic chloride formed
is immediately hydrolized into hydrochloric acid and the hydrate of
stannic acid. The latter prevents the aggregation of the gold
particles, and the stannic acid remains in solution as a colloid,
which on standing gradually changes under the influence of the dilute
hydrochloric acid to an insoluble form, the "hydrogel" of stannic
acid. By heating, this change takes place immediately. The properties
of the purple of Cassius depend on the properties and character of the
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