In a portrait studio ARTIFICIAL LIGHT IN PHOTOGRAPHY] [Illustration: Swimming pool City waterworks STERILIZING WATER WITH RADIANT ENERGY FROM QUARTZ MERCURY-ARCS] Although it appears that the chemical action of light was known to the ancients, the earliest photochemical investigations which could be considered scientific and systematic were those of K. W. Scheele in 1777 on silver salts. An extract from his own account is as follows: I precipitated a solution of silver by sal-ammoniac; then I edulcorated (washed) it and dried the precipitate and exposed it to the beams of the sun for two weeks; after which I stirred the powder and repeated the same several times. Hereupon I poured some caustic spirit of sal-ammoniac (strong ammonia) on this, in all appearance, black powder, and set it by for digestion. This menstruum (solvent) dissolved a quantity of luna cornua (horn silver), though some black powder remained undissolved. The powder having been washed was, for the greater part, dissolved by a pure acid of nitre (nitric acid), which, by the operation, acquired volatility. This solution I precipitated again by means of sal-ammoniac into horn silver. Hence it follows that the blackness which the luna cornua acquires from the sun's light, and likewise the solution of silver poured on chalk, is _silver by reduction_. I mixed so much of distilled water with the well-washed horn silver as would just cover this powder. The half of this mixture I poured into a white crystal phial, exposed it to the beams of the sun, and shook it several times each day; the other half I set in a dark place. After having exposed the one mixture during the space of two weeks, I filtrated the water standing over the horn silver, grown already black; I let some of this water fall by drops in a solution of silver, which was immediately precipitated into horn silver.