British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
At the commencement of this article, it was stated that silicic acid,
or silica, could be made soluble in water. Some very interesting
experiments were performed by the late Dr. Graham, Master of the Mint,
which gave rise to the discovery of the process of dialysis. If some
silicate of soda be mixed with water, so that not more than 5 per
cent. of silica be in the solution (rather less is better), and if
some hydrochloric acid be then added in sufficient quantity to make
the liquid distinctly acid, and the mixture be placed in a dialyzing
apparatus, the chloride of sodium formed by the union of the chlorine
of the hydrochloric acid with the sodium of the silicate of soda will
pass out through this dialyzing membrane, leaving hydrated silica
behind, which will remain in solution in the water with which the
silicate was mixed. The dialyzing apparatus is constructed in the
following manner; a sort of tambourine ring is made with gutta percha,
in place of wood, from 8 to 10 inches or even more in diameter, the
depth, being about 2 inches. Another ring of gutta percha, of about an
inch deep or even less, is made so as to fit tightly outside the
tambourine; a piece of vegetable parchment is then moistened and
placed over the tambourine, and the thinner ring is pressed over it,
so as to secure it tightly. This is the dialyzing vessel, and it is
into this that the mixture of silicate and hydrochloric acid must be
put. The solution should not be more than an inch deep in the
dialyzing vessel, which is then made to float upon distilled water in
a larger vessel of suitable size. The distilled water should be
changed every day, until no precipitate can be obtained in it with
nitrate of silver, and when this point is arrived at, all the chloride
of sodium will have passed through the vegetable parchment into the
larger vessel of water, and nothing but silicic hydrate will remain
behind in solution. If this liquid be allowed to stand for some time,
it will gelatinize, and later on the jelly will contract, becoming
extremely hard, so that lumps of it, when broken, will in their
fracture resemble that of flint. No doubt, at some future period, some
one will discover a method of rendering this condition of silica
useful in the arts.
Soluble silicates are very useful as detergents. A small quantity of
silicate of soda mixed with hard water renders it valuable for washing
purposes. Silicate of soda is also used in the manufacture of the
cheaper kinds of soap. We can hardly speak of it as an adulteration,
because it renders the soap with which it is combined much more
powerful in its cleansing action. I suggest to those interested in the
application of science to the arts, that this subject will no doubt
well repay experimental investigations.
Public-domain text, read in full here on John Shaqi.
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