British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
of gold glass; the whole mass is heated until both become soft, and is
then blown and formed into sheet, which, on examination, will be found
to consist mainly of white glass, with its surface thinly covered with
the glass stained with oxide of gold, while the beautiful ruby colour,
which the gold imparts to the glass, appears pure and distinct. If
such glass as this be heated to too high a temperature, as when it is
used in the manufacture of stained glass windows, the ruby colour is
in part, and sometimes altogether, destroyed, for the oxide of gold
loses its oxygen, and metallic gold is left behind, which does not
yield a colour to the silicate. I have in my possession a piece of
French glass of a pale sapphire tint, which, when heated in the
oxidizing flame of the blowpipe, assumes a brilliant and intense ruby
colour, showing that in the first condition, the gold is not in a
state of oxidation sufficient to impart colour to the glass.
When the suboxide of copper is mixed and fused with the glass which it
is intended to colour, the result is an opaque substance, almost like
red bottle-sealing-wax, which is treated in a manner exactly similar
to the gold glass; viz. it is coated with white glass, and blown and
shaped into sheets, which owe their intense ruby colour to a thin film
of the coloured glass closely adhering to the mass of the white upon
which it is placed. Glass made in this way is called "coated," and
sometimes "flashed" glass, and is extremely useful for ornamental
purposes, for by the action upon the coloured surface of hydrofluoric
acid, the ruby coating can be eaten away, and the white glass beneath
left entire. If the backgrounds of the patterns be painted upon the
ruby side with a material like Brunswick black, which is able to
resist the action of hydrofluoric acid, and if the plate of glass, on
its ruby side, be exposed to the action of the vapour of this acid, or
to the action of the acid in solution in water, in a short space of
time the pattern will be eaten away; and if the Brunswick black
coating be removed with turpentine, a sheet of ruby glass will be
obtained with a white pattern etched upon it.
Owing to the powerful colouring properties which oxide of cobalt
exerts, a very deep-coloured blue glass can be made, which can be
treated like the red copper glass, and may be made to coat and cover
in the same way the surface of plates of white glass. Purple glass,
coloured with oxide of manganese, and green glass are also sometimes
used as coating materials for white glass, but other colours are never
employed in this way.
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